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Deactivation Features of Gallium-Containing Zeolites in the Propane Aromatization Process Full article

Journal Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1531-8532
Output data Year: 2017, Volume: 57, Number: 1, Pages: 85-92 Pages count : 8 DOI: 10.1134/S0965544116090231
Tags activity, aromatic hydrocarbons, carbon deposits, coke, conversion, propane, selectivity, zeolite
Authors Vosmerikova L.N. 1 , Zaikovskii V.I. 2,3 , Volynkina A.N. 1 , Vosmerikov A.V. 1
Affiliations
1 Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences, Tomsk, 634055 Russia
2 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
3 Novosibirsk State University, Novosibirsk, 630090 Russia

Abstract: Conversion of propane to aromatic hydrocarbons on Ga-containing zeolite catalysts prepared by various methods has been examined, and their comparative stability against deactivation has been analyzed. It has been shown that the Ga-containing zeolite catalysts exhibit high activity and stability in propane conversion to aromatic hydrocarbons. Specific features of the formation of carbon deposits on the surface of Ga-containing zeolites in the propane aromatization reaction have been revealed using the techniques of temperature-programmed desorption of ammonia, low-temperature adsorption of nitrogen, differential thermal analysis, high-resolution transmission electron microscopy, and characteristic X-ray spectroscopy radiation. It has been found that the coke deposited on the catalyst has an almost homogeneous structure and is characterized by relatively low degree of polycondensation.
Cite: Vosmerikova L.N. , Zaikovskii V.I. , Volynkina A.N. , Vosmerikov A.V.
Deactivation Features of Gallium-Containing Zeolites in the Propane Aromatization Process
Petroleum Chemistry. 2017. V.57. N1. P.85-92. DOI: 10.1134/S0965544116090231 WOS Scopus РИНЦ AN OpenAlex
Original: Восьмерикова Л.Н. , Зайковский В.И. , Волынкина А.Н. , Восьмериков А.В.
Особенности дезактивации Ga-содержащих цеолитов в процессе ароматизации пропана
Нефтехимия. 2017. Т.57. №1. С.88-95. DOI: 10.7868/S002824211606023X РИНЦ
Dates:
Submitted: Mar 31, 2016
Published print: Jan 1, 2017
Published online: Feb 12, 2017
Identifiers:
Web of science: WOS:000394356700010
Scopus: 2-s2.0-85012910964
Elibrary: 29485015
Chemical Abstracts: 2017:274706
OpenAlex: W2587528178
Citing:
DB Citing
Web of science 5
Scopus 4
Elibrary 4
OpenAlex 4
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