Granulated Rhodium Catalysts of Sodium Borohydride Hydrolysis for Generators of High-Purity Hydrogen | Sciact - CRIS-system of Boreskov Institute of Catalysis

Granulated Rhodium Catalysts of Sodium Borohydride Hydrolysis for Generators of High-Purity Hydrogen Full article

Journal

Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296

Output data

Year: 2016, Volume: 89, Number: 10, Pages: 1625-1631 Pages count : 7 DOI: 10.1134/S1070427216100104

Funding (1)

Federal Agency for Scientific Organizations

0303-2015-0002

Sodium borohydride hydrolysis in a flow reactor with turbulent mixing of reactants in a catalytic bed by the evolving hydrogen bubbles was studied. The stability of catalytic systems decreases in the order 1% Rh/Sibunit > 1% Rh/TiO2 > 1% Rh/γ-Al2O3. The decrease in the hydrogen generation rate is caused by the formation of a metaborate film on the catalyst surface, by the loss of the active component, and by disintegration of support granules and their removal with the flow of the spent liquid. High granule strength and macroporous structure of 1% Rh/Sibunit ensure stable generation of hydrogen.

Netskina O.V. , Komova O.V. , Simagina V.I.
Granulated Rhodium Catalysts of Sodium Borohydride Hydrolysis for Generators of High-Purity Hydrogen
Russian Journal of Applied Chemistry. 2016. V.89. N10. P.1625-1631. DOI: 10.1134/S1070427216100104 WOS Scopus РИНЦ ANCAN OpenAlex

Нецкина О.В. , Комова О.В. , Симагина В.И.
Гранулированные родиевые катализаторы гидролиза боргидрида натрия для генераторов высокочистого водорода
Журнал прикладной химии. 2016. Т.89. №10. С.1305-1311. РИНЦ

Published print:	Oct 1, 2016
Submitted:	Oct 5, 2016
Published online:	Feb 9, 2017

Web of science:	WOS:000394442100010
Scopus:	2-s2.0-85011811019
Elibrary:	29477563
Chemical Abstracts:	2017:248095
Chemical Abstracts (print):	166:276247
OpenAlex:	W2587071281

DB	Citing
Web of science	4
Scopus	4
Elibrary	4
OpenAlex	5