Catalytic Behavior of Bimetallic Ni-Fe Systems in Decomposition of 1,2-Dichloroethane. Effect of Iron Doping and Preparation Route | Sciact - CRIS-system of Boreskov Institute of Catalysis

Catalytic Behavior of Bimetallic Ni-Fe Systems in Decomposition of 1,2-Dichloroethane. Effect of Iron Doping and Preparation Route Full article

Journal

Reaction Kinetics, Mechanisms and Catalysis
ISSN: 1878-5190 , E-ISSN: 1878-5204

Output data

Year: 2017, Volume: 121, Number: 2, Pages: 413-423 Pages count : 11 DOI: 10.1007/s11144-017-1180-4

Tags

1,2-Dichlorethane, Bimetallic Ni–Fe systems, Carbon nanofibers, Decomposition, Metal dusting

Authors

Bauman Yuri I. ¹ , Kutaev Nikolay V. ² , Plyusnin Pavel E. ^2,3 , Mishakov Ilya V. ^1,4 , Shubin Yury V. ^2,3 , Vedyagin Aleksey A. ^1,4 , Buyanov Roman A. ¹

Affiliations

1	Boreskov Institute of Catalysis SB RAS, pr. Ac. Lavrentieva, 5, Novosibirsk, Russian Federation 630090
2	Novosibirsk State University, Pirogova str., 2, Novosibirsk, Russian Federation 630090
3	Nikolaev Institute of Inorganic Chemistry SB RAS, pr. Ac. Lavrentieva 3, Novosibirsk, Russian Federation 630090
4	National Research Tomsk Polytechnic University, Lenin av., 30, Tomsk, Russian Federation 634050

Funding (1)

Russian Foundation for Basic Research

16-33-60074

Model bimetallic Ni–Fe catalysts were prepared by coprecipitation from aqueous solutions of nitrates and by mechanical alloying of metal powders. Pure nickel samples subjected to the similar procedures were used as references. The obtained samples were characterized by scanning electron microscopy and X-ray diffraction analysis. Catalytic chemical vapor deposition of 1,2-dichloroethane over the catalysts was studied in a quartz flow reactor equipped with a McBain balance. It was shown that in the case of coprecipitation followed by reduction, Ni–Fe solid solution is formed within the studied range of Fe loading (1–10 wt%). Activation times of 6 min and longer are required to obtain this solid solution by the mechanical alloying method. Despite the known catalytic activity of nickel and iron in hydrocarbon decomposition in accordance with carbide cycle mechanism, iron doping was found to worsen the behavior of nickel in the studied reaction where chlorinated alkane plays a role of substrate to be decomposed. The formation of thermodynamically more stable iron chloride in relation to nickel chloride leads to deactivation of the catalyst and deceleration of the overall process.

Bauman Y.I. , Kutaev N.V. , Plyusnin P.E. , Mishakov I.V. , Shubin Y.V. , Vedyagin A.A. , Buyanov R.A.
Catalytic Behavior of Bimetallic Ni-Fe Systems in Decomposition of 1,2-Dichloroethane. Effect of Iron Doping and Preparation Route
Reaction Kinetics, Mechanisms and Catalysis. 2017. V.121. N2. P.413-423. DOI: 10.1007/s11144-017-1180-4 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Jan 15, 2017
Accepted:	Apr 4, 2017
Published online:	Apr 10, 2017
Published print:	Aug 1, 2017

Web of science:	WOS:000405582300004
Scopus:	2-s2.0-85017398392
Elibrary:	31035614
Chemical Abstracts:	2017:598278
OpenAlex:	W2607233535

DB	Citing
Web of science	8
Scopus	9
Elibrary	10
OpenAlex	9