Effect of the Structure of Titanium-Magnesium Catalysts on the Morphology of Polyethylene Produced Научная публикация
| Журнал |
Journal of Polymer Science, Part A: Polymer Chemistry
ISSN: 0887-624X , E-ISSN: 1099-0518 |
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| Вых. Данные | Год: 2017, Том: 55, Номер: 14, Страницы: 2298-2308 Страниц : 11 DOI: 10.1002/pola.28614 | ||||
| Ключевые слова | catalysts, morphology, polyethylene (PE), pore structure, scanning electron microscopy (SEM), structure-property relations, structure–property relation, Ziegler-Natta polymerization | ||||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Федеральное агентство научных организаций России | 0303-2016-0009 |
Реферат:
The structure and formation of polyethylene (PE) particles on supported titanium–magnesium catalysts having different structural characteristics (sizes of microcrystallites, mesopores, and subparticles) were studied for the first time. Scanning electron microscopy was used to identify structural elements of the polymer particles formed over such catalysts and to reveal morphological changes in the growing polymer particles when the yield was increased from approximately 0.2 g PE/g catalyst to approximately 13 kg PE/g catalyst. A relationship was found between structural characteristics of the porous catalyst particles, morphology of the nascent polymer particles, and bulk density of the polymer powder.
Библиографическая ссылка:
Mikenas T.B.
, Koshevoy E.I.
, Zakharov V.A.
Effect of the Structure of Titanium-Magnesium Catalysts on the Morphology of Polyethylene Produced
Journal of Polymer Science, Part A: Polymer Chemistry. 2017. V.55. N14. P.2298-2308. DOI: 10.1002/pola.28614 WOS Scopus РИНЦ OpenAlex CAPlusCA
Effect of the Structure of Titanium-Magnesium Catalysts on the Morphology of Polyethylene Produced
Journal of Polymer Science, Part A: Polymer Chemistry. 2017. V.55. N14. P.2298-2308. DOI: 10.1002/pola.28614 WOS Scopus РИНЦ OpenAlex CAPlusCA
Даты:
| Поступила в редакцию: | 7 мар. 2017 г. |
| Принята к публикации: | 2 апр. 2017 г. |
| Опубликована online: | 21 апр. 2017 г. |
| Опубликована в печати: | 15 июн. 2017 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:000402682000004 |
| ≡ Scopus: | 2-s2.0-85018641850 |
| ≡ РИНЦ: | 31038109 |
| ≡ OpenAlex: | W2606688259 |
| ≡ Chemical Abstracts: | 2017:630916 |
| ≡ Chemical Abstracts (print): | 166:549631 |