The Chemical Composition and Structure of Supported Sulfated Zirconia with Regulated Size Nanoparticles Full article
| Conference |
X-Ray Absorption Fine Structure : 13th International Conference 09-14 Jul 2006 , Stanford, CA |
||||||
|---|---|---|---|---|---|---|---|
| Source | X-ray Absorption Fine Structure - XAFS13: 13th International Conference Compilation, American Institute of Physics. 2007. 959 c. ISBN 9780735403840. |
||||||
| Journal |
AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616 |
||||||
| Output data | Year: 2007, Volume: 882, Pages: 648-650 Pages count : 3 DOI: 10.1063/1.2644619 | ||||||
| Tags | EXAFS, Skeletal isomerization catalysts, Sulfated zirconia supported on titania | ||||||
| Authors |
|
||||||
| Affiliations |
|
Funding (3)
| 1 | Russian Foundation for Basic Research | 05-03-32326 |
| 2 | Civilian Research and Development Foundation | NO-008-X1 |
| 3 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | 00-00863 |
Abstract:
A set of model skeletal isomerization catalysts — sulfated zirconia nanoparticles of controlled thickness anchored on different supports — was prepared using colloidal solutions of Zr salt on titania as support. The nanoparticles of zirconia (1–5 nm) are epitaxially connected to the support surface, with S/Zr ratio equals to 1.3–1.5. It was shown by EXAFS that nanoparticles of non‐stoichiometric zirconium sulfate Zr(SO4)1+x, where x<0.5, are formed on the support surface. Its structure looks like half‐period shifted counterdirected chains built‐up by zirconium atoms linked by triangle pyramids of sulfate groups. Considering catalytic data of skeletal n‐butane isomerisation at 150°C, one can suggest that these species behave as the active component of sulfated zirconia. They are formed in subsurface layers as zirconium hydroxide undergoes sulfation followed by thermal treatment.
Cite:
Kanazhevskiy V.V.
, Shmachkova V.P.
, Kotsarenko N.S.
, Kochubey D.I.
, Vedrine J.C.
The Chemical Composition and Structure of Supported Sulfated Zirconia with Regulated Size Nanoparticles
In compilation X-ray Absorption Fine Structure - XAFS13: 13th International Conference. – American Institute of Physics., 2007. – C.648-650. – ISBN 9780735403840. DOI: 10.1063/1.2644619 WOS Scopus РИНЦ ANCAN OpenAlex
The Chemical Composition and Structure of Supported Sulfated Zirconia with Regulated Size Nanoparticles
In compilation X-ray Absorption Fine Structure - XAFS13: 13th International Conference. – American Institute of Physics., 2007. – C.648-650. – ISBN 9780735403840. DOI: 10.1063/1.2644619 WOS Scopus РИНЦ ANCAN OpenAlex
Identifiers:
| Web of science: | WOS:000245805900193 |
| Scopus: | 2-s2.0-33947425165 |
| Elibrary: | 15049569 |
| Chemical Abstracts: | 2007:348400 |
| Chemical Abstracts (print): | 147:102785 |
| OpenAlex: | W1608277798 |
Citing:
Пока нет цитирований