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Anisotropic Properties of Carbonaceous Material Produced in Arc Discharge Full article

Journal Applied Physics A: Materials Science and Processing
ISSN: 0947-8396 , E-ISSN: 1432-0630
Output data Year: 2001, Volume: 72, Number: 4, Pages: 481-486 Pages count : 6 DOI: 10.1007/s003390100564
Tags Anisotropy; Chemical bonds; Electric conductivity measurement; Electron microscopy; Fluorescence; Pressure effects; X ray spectroscopy
Authors Okotrub A.V. 1 , Bulusheva L.G. 1 , Romanenko A.I. 1 , Chuvilin A.L. 2 , Rudina N.A. 2 , Shubin Y.V. 1 , Yudanov N.F. 1 , Guselʹnikov A.V. 1
Affiliations
1 Institute of Inorganic Chemistry SB RAS, pr. Ak. Lavrenteva 3, Novosibirsk 630090, Russia
2 Boreskov Institute of Catalysis SB RAS, pr. Ak. Lavrenteva 5, Novosibirsk 630090, Russia

Funding (3)

1 Russian Foundation for Basic Research 00-02-17987
2 Russian Foundation for Basic Research 00-03-32463
3 International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union 97-1700

Abstract: A helium-pressure influence on the structure and properties of carbonaceous material from the inner part of a deposit forming in an arc discharge has been studied. At the helium pressure of about 150 Torr and higher, the material was found to have a layered texture, which is perpendicular to the deposit growth axis. Electron microscopy measurements showed that a sample produced in He gas of 800 Torr consists of ∼ 80% carbon nanotubes having predominant orientation in the layers. Electric conductivity along and perpendicular to the samples’ surface have been measured from 4.2 to 500 K. The samples synthesised at higher helium pressures have significant anisotropy of conductivity, increasing with the carbon nanotubes content rise. X-ray fluorescence spectra represented the angle dependence that is caused by the anisotropy of chemical bonding in the carbon nanotubes. The valence π- and σ-bands for the carbonaceous material were separated.
Cite: Okotrub A.V. , Bulusheva L.G. , Romanenko A.I. , Chuvilin A.L. , Rudina N.A. , Shubin Y.V. , Yudanov N.F. , Guselʹnikov A.V.
Anisotropic Properties of Carbonaceous Material Produced in Arc Discharge
Applied Physics A: Materials Science and Processing. 2001. V.72. N4. P.481-486. DOI: 10.1007/s003390100564 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Nov 26, 1999
Accepted: Apr 20, 2000
Published online: Jan 10, 2001
Published print: Apr 1, 2001
Identifiers:
Web of science: WOS:000167840200013
Scopus: 2-s2.0-0034974016
Elibrary: 13375546
Chemical Abstracts: 2001:262695
Chemical Abstracts (print): 134:374752
OpenAlex: W2092885910
Citing:
DB Citing
Web of science 29
Scopus 25
Elibrary 27
OpenAlex 27
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