Interaction of Bulk Nickel and Nichrome with Halogenated Butanes | Sciact - CRIS-system of Boreskov Institute of Catalysis

Interaction of Bulk Nickel and Nichrome with Halogenated Butanes Full article

Journal

Reaction Kinetics, Mechanisms and Catalysis
ISSN: 1878-5190 , E-ISSN: 1878-5204

Output data

Year: 2017, Volume: 122, Number: 2, Pages: 1203-1212 Pages count : 10 DOI: 10.1007/s11144-017-1273-0

Tags

Ferromagnetic resonance, Halogenated hydrocarbons, Intermediates, RAPET conditions, Self-disintegration of bulk alloys

Authors

Kenzhin Roman M. ¹ , Bauman Yuri I. ¹ , Volodin Alexander M. ¹ , Mishakov Ilya V. ^1,2 , Vedyagin Aleksey A. ^1,2

Affiliations

1	Boreskov Institute of Catalysis SB RAS, pr. Ac. Lavrentieva, 5, Novosibirsk, Russian Federation 630090
2	National Research Tomsk Polytechnic University, Lenin Av., 30, Tomsk, Russian Federation 634050

Funding (1)

Russian Foundation for Basic Research

16-33-60034

Catalytic chemical vapor deposition of halogenated butanes over bulk nickel-containing samples was studied. Butyl iodide and butyl bromide were used as substrates containing both hydrogen and halogen molecules. The experiments were performed in a flow reactor system as well as under Autogenic Pressure at Elevated Temperature (RAPET) conditions. Scanning and transmission electron microscopies and ferromagnetic resonance spectroscopy were applied to examine the samples. Formation of structured particles of micron size was observed when nickel ribbon or nichrome wire was used as a bulk sample. The intermediates were shown to be stable in a narrow temperature range. The morphology of resulting microcrystals was different depending on the metal precursor.

Kenzhin R.M. , Bauman Y.I. , Volodin A.M. , Mishakov I.V. , Vedyagin A.A.
Interaction of Bulk Nickel and Nichrome with Halogenated Butanes
Reaction Kinetics, Mechanisms and Catalysis. 2017. V.122. N2. P.1203-1212. DOI: 10.1007/s11144-017-1273-0 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Jun 27, 2017
Accepted:	Sep 16, 2017
Published online:	Sep 26, 2017
Published print:	Dec 1, 2017

Web of science:	WOS:000413845800036
Scopus:	2-s2.0-85029906406
Elibrary:	31057350
Chemical Abstracts:	2017:1612597
OpenAlex:	W2757438810

DB	Citing
Web of science	4
Scopus	5
Elibrary	5
OpenAlex	7