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Chiral Manganese Aminopyridine Complexes: the Versatile Catalysts of Chemo- and Stereoselective Oxidations with H2O2 Full article

Journal Chemical Record
ISSN: 1527-8999 , E-ISSN: 1528-0691
Output data Year: 2018, Volume: 18, Number: 1, Pages: 78-90 Pages count : 13 DOI: 10.1002/tcr.201700032
Tags asymmetric epoxidation, C−H oxidation, hydrogen peroxide, manganese, mechanism
Authors Ottenbacher Roman V. 1,2 , Talsi Evgenii P. 1,2 , Bryliakov Konstantin P. 1,2
Affiliations
1 Chemistry Department, Novosibirsk State University, Pirogova 2, Novosibirsk 630090 (Russia)
2 Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090 (Russia)

Funding (2)

1 Russian Science Foundation 17-13-01117
2 Russian Foundation for Basic Research 16-33-00014

Abstract: In the last decade, manganese(II) complexes with N-donor tetradentate aminopyridine ligands emerged as efficient catalysts of enantioselective epoxidation of olefins and direct selective oxidation of C−H groups in complex organic molecules, with environmentally benign oxidant hydrogen peroxide. In this personal account, we summarize the progress of these catalysts with regard to ligands design, structure-reactivity correlations, evaluation of the substrate scope, as well as mechanistic studies, shedding light on the nature of active sites and the mechanisms of selective oxygenations. Several practically promising catalytic syntheses with the aid of Mn aminopyridine catalysts are exemplified.
Cite: Ottenbacher R.V. , Talsi E.P. , Bryliakov K.P.
Chiral Manganese Aminopyridine Complexes: the Versatile Catalysts of Chemo- and Stereoselective Oxidations with H2O2
Chemical Record. 2018. V.18. N1. P.78-90. DOI: 10.1002/tcr.201700032 WOS Scopus РИНЦ AN PMID OpenAlex
Dates:
Submitted: May 10, 2017
Published online: Jul 14, 2017
Published print: Jan 1, 2018
Identifiers:
Web of science: WOS:000419935300007
Scopus: 2-s2.0-85025171244
Elibrary: 35513224
Chemical Abstracts: 2017:1176039
PMID: 28707370
OpenAlex: W2734658276
Citing:
DB Citing
Web of science 47
Scopus 50
Elibrary 43
OpenAlex 51
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