Chiral Manganese Aminopyridine Complexes: the Versatile Catalysts of Chemo- and Stereoselective Oxidations with H2O2 Full article
| Journal |
Chemical Record
ISSN: 1527-8999 , E-ISSN: 1528-0691 |
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| Output data | Year: 2018, Volume: 18, Number: 1, Pages: 78-90 Pages count : 13 DOI: 10.1002/tcr.201700032 | ||||
| Tags | asymmetric epoxidation, C−H oxidation, hydrogen peroxide, manganese, mechanism | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Science Foundation | 17-13-01117 |
| 2 | Russian Foundation for Basic Research | 16-33-00014 |
Abstract:
In the last decade, manganese(II) complexes with N-donor tetradentate aminopyridine ligands emerged as efficient catalysts of enantioselective epoxidation of olefins and direct selective oxidation of C−H groups in complex organic molecules, with environmentally benign oxidant hydrogen peroxide. In this personal account, we summarize the progress of these catalysts with regard to ligands design, structure-reactivity correlations, evaluation of the substrate scope, as well as mechanistic studies, shedding light on the nature of active sites and the mechanisms of selective oxygenations. Several practically promising catalytic syntheses with the aid of Mn aminopyridine catalysts are exemplified.
Cite:
Ottenbacher R.V.
, Talsi E.P.
, Bryliakov K.P.
Chiral Manganese Aminopyridine Complexes: the Versatile Catalysts of Chemo- and Stereoselective Oxidations with H2O2
Chemical Record. 2018. V.18. N1. P.78-90. DOI: 10.1002/tcr.201700032 WOS Scopus РИНЦ AN PMID OpenAlex
Chiral Manganese Aminopyridine Complexes: the Versatile Catalysts of Chemo- and Stereoselective Oxidations with H2O2
Chemical Record. 2018. V.18. N1. P.78-90. DOI: 10.1002/tcr.201700032 WOS Scopus РИНЦ AN PMID OpenAlex
Dates:
| Submitted: | May 10, 2017 |
| Published online: | Jul 14, 2017 |
| Published print: | Jan 1, 2018 |
Identifiers:
| Web of science: | WOS:000419935300007 |
| Scopus: | 2-s2.0-85025171244 |
| Elibrary: | 35513224 |
| Chemical Abstracts: | 2017:1176039 |
| PMID: | 28707370 |
| OpenAlex: | W2734658276 |