Study of the Mechanisms of the Catalytic Decomposition of Hydrogen Peroxide, by the MO LCAO Method | Sciact - CRIS-system of Boreskov Institute of Catalysis

Study of the Mechanisms of the Catalytic Decomposition of Hydrogen Peroxide, by the MO LCAO Method Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 1969, Volume: 10, Number: 6-1, Pages: 1043-1046 Pages count : 4

Tags

Catalysis; CHEMICAL REACTIONS, DECOMPOSIT; Hydrogen peroxide; KICAA; PEROXIDE

Authors

Chernyavskii L.I. ¹ , Sutula V.D. ¹

Affiliations

1	Institute of Catalysis, Academy of Sciences of the USSR

Two mechanisms for the decomposition of H2O2-the radical- chain and the nonradical mechanisms-have been examined. It has been shown by calculations of the orbital energy along the assumed reaction paths by means of the extended Hueckel method that the radical-chain mechanism is facilitated by the existence of filled catalyst level, situated not lower than the upper half-filled level of the OH. The nonradical mechanism of decomposition, which involves the complex H4O4, according to the results of the calculations, requires the existence of an empty catalyst level and special steric conditions.

Chernyavskii L.I. , Sutula V.D.
Study of the Mechanisms of the Catalytic Decomposition of Hydrogen Peroxide, by the MO LCAO Method
Kinetics and Catalysis. 1969. V.10. N6-1. P.1043-1046. Scopus РИНЦ

Чернявский Л.И. , Сутула В.Д.
Изучение механизмов каталитического разложения перекиси водорода с помощью метода МОЛКАО
Кинетика и катализ. 1969. Т.10. №6. С.1264-1269. РИНЦ ANCAN

Published print:

Nov 1, 1969

Scopus:	2-s2.0-0014595113
Elibrary:	30298099

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