Understanding the Regioselectivity of Aromatic Hydroxylation Over Divanadium-Substituted γ-Keggin Polyoxotungstate Научная публикация
| Журнал |
ACS Catalysis
ISSN: 2155-5435 |
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| Вых. Данные | Год: 2017, Том: 7, Номер: 12, Страницы: 8514-8523 Страниц : 10 DOI: 10.1021/acscatal.7b02694 | ||||||
| Ключевые слова | aromatic hydroxylation, DFT, homogeneous catalysis, hydrogen peroxide, kinetic-modeling, polyoxometalate, pseudocumene, vanadium | ||||||
| Авторы |
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| Организации |
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Информация о финансировании (3)
| 1 | Федеральное агентство научных организаций России | 0303-2016-0005 |
| 2 | Government of Catalonia | 2014SGR199 |
| 3 | Ministry of Economic Affairs and Digital Transformation | CTQ2014-52774-P |
Реферат:
The aromatic hydroxylation of pseudocumene (PC) with aqueous hydrogen peroxide catalyzed by the divanadium-substituted γ-Keggin polyoxotungstate TBA4[γ-PW10O38V2(µ-O)(µ-OH)] (TBA-1H, TBA = tetrabutylammonium) has been studied using kinetic modeling and DFT calculations. This reaction features high chemoselectivity and unusual regioselectivity, affording 2,4,5-trimethylphenol (TMP) as the main product. Then the computational study was extended to the analysis of the regioselectivity for other alkoxy- and alkylarene substrates. The protonation/deprotonation of TBA-1H in MeCN/tBuOH (1:1) was investigated by the 31P NMR spectroscopy. Forms with different protonation state, [γ-PV2W10O40]5- (1), [γ-HPV2W10O40]4- (1H) and [γ-H2PV2W10O40]3- (1H2), have been identified, and the protonation equilibrium constants were estimated on the basis of the 31P NMR data. DFT
calculations were used to investigate the oxygen transfer process from hydroperoxo species, [γ-PW10O38V2(µ-O)(µ-OOH)]4- (2) and [γ-PW10O38V2(µ-OH)(µ-OOH)]3- (2H), and peroxo complex [γ-PW10O38V2(µ-η2:η2-O2)]3- (3) toward the different positions in the aromatic ring of PC, anisole and toluene substrates. Product, kinetic, and computational studies on the PC hydroxylation strongly support a mechanism of electrophilic oxygen atom transfer from peroxo complex 3 to the aromatic ring of PC. The kinetic modeling revealed that contribution of 3 into the initial reaction rate is, on the average, about 70%, but it may depend on the reaction conditions. DFT calculations showed that the steric hindrance exerted by peroxo complex 3 is responsible of the origin of the unusual regioselectivity observed in PC hydroxylation, while for anisole and toluene the regioselective para-hydroxylation is due to electronic preference during the oxygen transfer from the active peroxo species 3.
Библиографическая ссылка:
Skobelev I.Y.
, Evtushok V.Y.
, Kholdeeva O.A.
, Maksimchuk N.V.
, Maksimovskaya R.I.
, Ricart J.M.
, Poblet J.M.
, Carbó J.J.
Understanding the Regioselectivity of Aromatic Hydroxylation Over Divanadium-Substituted γ-Keggin Polyoxotungstate
ACS Catalysis. 2017. V.7. N12. P.8514-8523. DOI: 10.1021/acscatal.7b02694 WOS Scopus РИНЦ CAPlusCA OpenAlex
Understanding the Regioselectivity of Aromatic Hydroxylation Over Divanadium-Substituted γ-Keggin Polyoxotungstate
ACS Catalysis. 2017. V.7. N12. P.8514-8523. DOI: 10.1021/acscatal.7b02694 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 10 авг. 2017 г. |
| Принята к публикации: | 2 нояб. 2017 г. |
| Опубликована online: | 15 нояб. 2017 г. |
| Опубликована в печати: | 1 дек. 2017 г. |
Идентификаторы БД:
| Web of science: | WOS:000417230500059 |
| Scopus: | 2-s2.0-85036669850 |
| РИНЦ: | 32259423 |
| Chemical Abstracts: | 2017:1754944 |
| Chemical Abstracts (print): | 168:337430 |
| OpenAlex: | W2765957838 |