Calculation of the E.S.R. Spectrum of a Dynamic Biradical System with More than Two Conformations Full article
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Molecular Physics
ISSN: 0026-8976 , E-ISSN: 1362-3028 |
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| Output data | Year: 1976, Volume: 32, Number: 3, Pages: 613-619 Pages count : 7 DOI: 10.1080/00268977600102081 | ||
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Abstract:
The E.S.R. spectrum of a biradical with any number of conformations is calculated. It is shown that in some cases the interpretation of the E.S.R. spectra of such biradicals can be carried out in terms of groups of the conformations with fast exchange inside the groups. It is shown also that in the case of fast exchange the averaging of describing spectrum parameters is performed over concentrations of the exchanging conformations but not over their lifetimes, as it was suggested earlier. A detailed treatment of the spectra of biradicals with three conformations is carried out, and the possibilities of the analysis of experimental spectra of long-chain nitroxide biradicals are shown.
Cite:
Parmon V.N.
, Zhidomirov G.M.
Calculation of the E.S.R. Spectrum of a Dynamic Biradical System with More than Two Conformations
Molecular Physics. 1976. V.32. N3. P.613-619. DOI: 10.1080/00268977600102081 WOS Scopus РИНЦ ANCAN OpenAlex
Calculation of the E.S.R. Spectrum of a Dynamic Biradical System with More than Two Conformations
Molecular Physics. 1976. V.32. N3. P.613-619. DOI: 10.1080/00268977600102081 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jan 5, 1976 |
| Accepted: | Mar 24, 1976 |
| Published print: | Sep 1, 1976 |
| Published online: | Aug 23, 2006 |
Identifiers:
| Web of science: | WOS:A1976CG55300002 |
| Scopus: | 2-s2.0-1642380796 |
| Elibrary: | 31110578 |
| Chemical Abstracts: | 1977:71577 |
| Chemical Abstracts (print): | 86:71577 |
| OpenAlex: | W2039986660 |