Fluidized-Bed Isobutane Dehydrogenation over Alumina-Supported Ga2O3 and Ga2O3-Cr2O3 Catalysts | Sciact - CRIS-system of Boreskov Institute of Catalysis

Fluidized-Bed Isobutane Dehydrogenation over Alumina-Supported Ga2O3 and Ga2O3-Cr2O3 Catalysts Full article

Journal

Industrial and Engineering Chemistry Research
ISSN: 0888-5885 , E-ISSN: 1520-5045

Output data

Year: 2018, Volume: 57, Number: 3, Pages: 927-938 Pages count : 12 DOI: 10.1021/acs.iecr.7b04571

Tags

CENTRIFUGAL THERMAL-ACTIVATION; GALLIUM OXIDE; PROPANE DEHYDROGENATION; PHYSICOCHEMICAL PROPERTIES; NANOPOROUS MATERIALS; PYRIDINE ADSORPTION; HAMMETT INDICATORS; LIGHT ALKANES; FLASH REACTOR; MIXED OXIDES

Authors

Matveyeva Anna N. ¹ , Zaitseva Nadezhda A. ³ , Mäki-Arvela Päivi ⁴ , Aho Atte ⁴ , Bachina Anastasia K. ² , Fedorov Sergey P. ¹ , Murzin Dmitry Yu. ^1,4 , Pakhomov Nikolai A. ¹

Affiliations

1	Laboratory of Catalytic Technologies, St. Petersburg State Institute of Technology, Technical University, Moskovsky Avenue 26, St. Petersburg, Russian Federation
2	Department of Physical Chemistry, St. Petersburg State Institute of Technology (Technical University), Moskovsky Avenue 26, St. Petersburg 190013, Russia
3	Boreskov Institute of Catalysis SB RAS, Novosibirsk 630090, Russia
4	Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, Biskopsgatan 8, Turku/Åbo 20500, Finland

Funding (1)

The Ministry of Education and Science of the Russian Federation

14.Z50.31.0013

Dehydrogenation of isobutane to isobutene over supported gallium oxide microspherical catalysts was investigated in a fluidized-bed reactor. A partially crystallized nanostructured aluminum hydroxide-oxide, which is a product of gibbsite centrifugal thermal activation (CTA) obtained using a CEFLAR technology, was used as a catalyst support. The structural and textural properties of Ga2O3/Al2O3 catalysts were characterized by a range of techniques including XRD, N2-physisorption, TPD of NH3 and CO2, IRS of adsorbed pyridine, and selective adsorption of a series of acid-base indicators. A Ga-Al oxide catalyst exhibited a stable performance close to activity of Cr-Al oxide catalysts not containing soluble hexavalent chromium. Upon addition of Cr2O3 (6 wt % of Cr), in amounts lower than in an industrial chromia/alumina catalyst (10.9% Cr), and 1% ZrO2 to 6%Ga/Al2O3 catalytic activity in isobutane dehydrogenation reaches the performance of the industrial KDM catalyst ("Sintez", Russia).

Matveyeva A.N. , Zaitseva N.A. , Mäki-Arvela P. , Aho A. , Bachina A.K. , Fedorov S.P. , Murzin D.Y. , Pakhomov N.A.
Fluidized-Bed Isobutane Dehydrogenation over Alumina-Supported Ga2O3 and Ga2O3-Cr2O3 Catalysts
Industrial and Engineering Chemistry Research. 2018. V.57. N3. P.927-938. DOI: 10.1021/acs.iecr.7b04571 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Nov 3, 2017
Accepted:	Dec 24, 2017
Published online:	Jan 11, 2018
Published print:	Jan 24, 2018

Web of science:	WOS:000423496400015
Scopus:	2-s2.0-85041198935
Elibrary:	35509987
Chemical Abstracts:	2017:2027083
Chemical Abstracts (print):	168:115011
OpenAlex:	W2779724764

DB	Citing
Web of science	19
Scopus	21
Elibrary	18
OpenAlex	19