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Temperature Hysteresis in the Reaction of Methane Oxidation on a Palladium-Doped Manganese Hexaaluminate Catalyst Full article

Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 2018, Volume: 59, Number: 1, Pages: 70-82 Pages count : 13 DOI: 10.1134/s0023158418010160
Tags manganese hexaaluminate, palladium doping, methane oxidation, thermal hysteresis, TPR-O2, in situ XRD analysis
Authors Yashnik S. A. 1 , Vinokurov Z. S. 1 , Salnikov A. V. 1 , Ishchenko A. V. 1 , Kaichev V. V. 1 , Ismagilov Z. R. 1,2
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2 Institute of Coal Chemistry and Chemical Materials Science, Siberian Branch, Russian Academy of Sciences, Kemerovo, Russia

Funding (1)

1 Russian Foundation for Basic Research 15-03-05459

Abstract: A study of the Pd-containing catalyst based on manganese hexaaluminate by X-ray diffraction analysis, transmission electron microscopy, thermo-programmed reduction with hydrogen, and thermoprogrammed oxidation showed the hysteresis manifested itself in a difference between the temperature dependences of its catalytic activity in the oxidation of methane under the conditions of sample heating or cooling is related to the decomposition of PdO to metallic palladium at temperatures higher than 700–800°C and the subsequent formation of PdO nanoparticles, which are localized on the surface of metallic Pd (30–50 nm) in the form of polycrystalline films with a thickness of 2–5 nm, at temperatures lower than 600–700°C. A near-surface oxide film is formed under the conditions of cooling in oxygen-containing atmospheres, including in the presence of methane. The value of the hysteresis depends on the heat treatment temperature of the catalyst, and it reaches a maximum on the catalysts calcined at 900 and 1000°C.
Cite: Yashnik S.A. , Vinokurov Z.S. , Salnikov A.V. , Ishchenko A.V. , Kaichev V.V. , Ismagilov Z.R.
Temperature Hysteresis in the Reaction of Methane Oxidation on a Palladium-Doped Manganese Hexaaluminate Catalyst
Kinetics and Catalysis. 2018. V.59. N1. P.70-82. DOI: 10.1134/s0023158418010160 WOS Scopus РИНЦ AN OpenAlex
Original: Яшник С.А. , Винокуров З.С. , Сальников А.В. , Ищенко А.В. , Каичев В.В. , Исмагилов З.Р.
Температурный гистерезис в реакции окисления метана на допированном палладием Mn-гексаалюминатном катализаторе
Кинетика и катализ. 2018. Т.59. №1. С.92-104. DOI: 10.7868/S0453881118010100 РИНЦ OpenAlex
Dates:
Submitted: Feb 20, 2017
Published print: Jan 1, 2018
Published online: Mar 6, 2018
Identifiers:
Web of science: WOS:000426796900008
Scopus: 2-s2.0-85043273073
Elibrary: 35496842
Chemical Abstracts: 2018:384901
OpenAlex: W2789260384
Citing:
DB Citing
Web of science 5
Scopus 3
Elibrary 4
OpenAlex 3
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