Transformation of a Pt-CeO2 Mechanical Mixture of Pulsed-Laser-Ablated Nanoparticles to a Highly Active Catalyst for Carbon Monoxide Oxidation | Sciact - CRIS-система Института катализа

Transformation of a Pt-CeO2 Mechanical Mixture of Pulsed-Laser-Ablated Nanoparticles to a Highly Active Catalyst for Carbon Monoxide Oxidation Научная публикация

Журнал

ChemCatChem
ISSN: 1867-3880 , E-ISSN: 1867-3899

Вых. Данные

Год: 2018, Том: 10, Номер: 10, Страницы: 2232-2247 Страниц : 16 DOI: 10.1002/cctc.201702050

Ключевые слова

Cerium, Laser chemistry, Nanoparticles, Oxidation, Platinum

Авторы

Slavinskaya E.M. ^1,2 , Stadnichenko A.I. ^1,2 , Muravyov V.V. ^1,2 , Kardash T.Y. ^1,2 , Derevyannikova E.A. ^1,2 , Zaikovskii V.I. ^1,2 , Stonkus O.A. ^1,2 , Lapin I.N. ³ , Svetlichnyi V.A. ³ , Boronin A.I. ^1,2

Организации

1	Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia
3	Tomsk State University, Tomsk, Russia

Информация о финансировании (2)

1	Федеральное агентство научных организаций России	0303-2016-0003
2	Российский фонд фундаментальных исследований	17-43-540738

The pulsed laser ablation (PLA) in alcohol and water media was employed to prepare Pt and CeO2 PLA-nanoparticles of different sizes and degrees of defectiveness. Interactions of metallic platinum and ceria particles were studied using the thermal activation of Pt-CeO2 mechanical mixtures in the CO+O2 reaction medium or O2 atmosphere. The thermal activation resulted in oxidized Pt2+/Pt4+ states of platinum in the surface solid solutions PtCeOx and/or PtOx clusters. Catalysts formed after calcination of the PLA-ablated Pt-CeO2 mixtures in oxygen at 450-600°C revealed CO conversion at very low temperatures up to 70% depending on the conditions of PLA particles preparation and thermal activation of Pt-CeO2 mechanical mixture.

Slavinskaya E.M. , Stadnichenko A.I. , Muravyov V.V. , Kardash T.Y. , Derevyannikova E.A. , Zaikovskii V.I. , Stonkus O.A. , Lapin I.N. , Svetlichnyi V.A. , Boronin A.I.
Transformation of a Pt-CeO2 Mechanical Mixture of Pulsed-Laser-Ablated Nanoparticles to a Highly Active Catalyst for Carbon Monoxide Oxidation
ChemCatChem. 2018. V.10. N10. P.2232-2247. DOI: 10.1002/cctc.201702050 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	27 дек. 2017 г.
Принята к публикации:	7 февр. 2018 г.
Опубликована online:	13 мар. 2018 г.
Опубликована в печати:	24 мая 2018 г.

Web of science:	WOS:000434071100013
Scopus:	2-s2.0-85043535462
РИНЦ:	35704073
Chemical Abstracts:	2018:466537
Chemical Abstracts (print):	169:215284
OpenAlex:	W2789283756

БД	Цитирований
Web of science	47
Scopus	48
РИНЦ	51
OpenAlex	47