Low-Temperature Phase Transition in Glycine-Glutaric Acid Co-Crystals Studied by Single-Crystal X-Ray Diffraction, Raman Spectroscopy and Differential Scanning Calorimetry | Sciact - CRIS-system of Boreskov Institute of Catalysis

Low-Temperature Phase Transition in Glycine-Glutaric Acid Co-Crystals Studied by Single-Crystal X-Ray Diffraction, Raman Spectroscopy and Differential Scanning Calorimetry Full article

Journal

Acta Crystallographica Section B. Structural Science (up to 2013)
ISSN: 0108-7681 , E-ISSN: 1600-5740

Output data

Year: 2012, Volume: 68, Number: 3, Pages: 287-296 Pages count : 10 DOI: 10.1107/S0108768112015972

Tags

phase transition; amino acid co-crystals; hydrogen bonds; single-crystal to single-crystal transformation; conformational polymorphism

Authors

Zakharov B.A. ^1,2 , Losev E.A. ^1,2 , Kolesov B.A. ^1,3 , Drebushchak V.A. ^1,4 , Boldyreva E.V. ^1,2

Affiliations

1	Institute of Solid State Chemistry and Mechanochemistry SB RAS, Novosibirsk, Russian Federation
2	REC-008 Novosibirsk State University, Novosibirsk, Russian Federation
3	Institute of Inorganic Chemistry SB RAS, Novosibirsk, Russian Federation
4	Institute of Geology and Mineralogy SB RAS, Russian Federation

The occurrence of a first-order reversible phase transition in glycine-glutaric acid co-crystals at 220-230 K has been confirmed by three different techniques - single-crystal X-ray diffraction, polarized Raman spectroscopy and differential scanning calorimetry. The most interesting feature of this phase transition is that every second glutaric acid molecule changes its conformation, and this fact results in the space-group symmetry change from P21/c to . The topology of the hydrogen-bonded motifs remains almost the same and hydrogen bonds do not switch to other atoms, although the hydrogen bond lengths do change and some of the bonds become inequivalent. © 2012 International Union of Crystallography Printed in Singapore - all rights reserved.

Zakharov B.A. , Losev E.A. , Kolesov B.A. , Drebushchak V.A. , Boldyreva E.V.
Low-Temperature Phase Transition in Glycine-Glutaric Acid Co-Crystals Studied by Single-Crystal X-Ray Diffraction, Raman Spectroscopy and Differential Scanning Calorimetry
Acta Crystallographica Section B. Structural Science (up to 2013). 2012. V.68. N3. P.287-296. DOI: 10.1107/S0108768112015972 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jan 31, 2012
Accepted:	Apr 12, 2012
Published online:	May 17, 2012
Published print:	Jun 1, 2012

Web of science:	WOS:000304250200008
Scopus:	2-s2.0-84861412624
Elibrary:	17986227
Chemical Abstracts:	2012:718378
Chemical Abstracts (print):	157:60380
OpenAlex:	W1968062068

DB	Citing
Web of science	34
Scopus	33
OpenAlex	27