Energy-Efficient Dehydrogenation of Methanol in a Membrane Reactor: A Mathematical Modeling Научная публикация
| Журнал |
Chemical Papers
ISSN: 0366-6352 , E-ISSN: 1336-9075 |
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| Вых. Данные | Год: 2018, Том: 72, Номер: 10, Страницы: 2617–2629 Страниц : 13 DOI: 10.1007/s11696-018-0491-x | ||||
| Ключевые слова | Methanol dehydrogenation; carbon-supported copper catalyst; catalytic membrane reactor; mathematical modeling; hydrogen oxidation; thermodynamically conjugated process | ||||
| Авторы |
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| Организации |
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Информация о финансировании (2)
| 1 | Федеральное агентство научных организаций России | 0303-2016-0014 |
| 2 | Министерство образования и науки Российской Федерации | VIU-TOVPM-316/2017 |
Реферат:
A two-dimensional non-isothermal stationary mathematical model of the catalytic membrane reactor for the process of methanol dehydrogenation is described. Copper supported on the carbonaceous support was considered as a catalyst. The reaction of methanol dehydrogenation was thermodynamically conjugated with a reaction of hydrogen oxidation taking place in a shell side of the membrane reactor. The effects of various parameters on the methanol conversion and the methyl formate yield have been calculated with the developed model and discussed. Two different types of heating the gas flow were considered and compared. In the case of conjugated dehydrogenation process, the methyl formate yield reaches 77%, when the reactor outer wall was heated up to 150 °C. When the inlet gas flows in the tube and shell sides were heated up to 100 and 83 °C, correspondingly, the yield was 72%.
Библиографическая ссылка:
Shelepova E.
, Ilina L.
, Vedyagin A.
Energy-Efficient Dehydrogenation of Methanol in a Membrane Reactor: A Mathematical Modeling
Chemical Papers. 2018. V.72. N10. P.2617–2629. DOI: 10.1007/s11696-018-0491-x WOS Scopus РИНЦ CAPlus OpenAlex
Energy-Efficient Dehydrogenation of Methanol in a Membrane Reactor: A Mathematical Modeling
Chemical Papers. 2018. V.72. N10. P.2617–2629. DOI: 10.1007/s11696-018-0491-x WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
| Поступила в редакцию: | 2 дек. 2017 г. |
| Принята к публикации: | 26 апр. 2018 г. |
| Опубликована online: | 4 мая 2018 г. |
| Опубликована в печати: | 1 окт. 2018 г. |
Идентификаторы БД:
| Web of science: | WOS:000441004300019 |
| Scopus: | 2-s2.0-85051217483 |
| РИНЦ: | 35722032 |
| Chemical Abstracts: | 2018:904846 |
| OpenAlex: | W2799462417 |