Design of Ag-CeO2/SiO2 Catalyst for Oxidative Dehydrogenation of Ethanol: Control of Ag–CeO2 Interfacial Interaction Научная публикация
| Журнал |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
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| Вых. Данные | Год: 2019, Том: 333, Страницы: 2-9 Страниц : 8 DOI: 10.1016/j.cattod.2018.05.014 | ||||||||
| Ключевые слова | silver, ceria, oxidative dehydrogenation of ethanol, Ag–CeO2 interaction | ||||||||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Министерство образования и науки Российской Федерации | МК-2015.2017.3 |
Реферат:
Three Ag-CeO2/SiO2 catalysts were prepared by different methods, namely, sequential impregnation, co-impregnation and impregnation of pre-reduced CeO2/SiO2 and are tested in the oxidative dehydrogenation of ethanol. The order of introduction of silver and ceria precursors is found to influence the catalytic activity that increases in the order of preparation method: sequential impregnation < co-impregnation < impregnation of pre-reduced CeO2/SiO2. Results of TPR-H2, TEM HR, XPS and Raman characterizations show the best interfacial Ag–CeO2 interaction and highest defectiveness of CeO2 nanoparticles in the catalyst prepared by impregnation of pre-reduced CeO2/SiO2. A correlation between Ag–CeO2 interaction and catalytic activity is found in the series of Ag-CeO2/SiO2 catalysts depending on the preparation method. Enhanced Ag–CeO2 interfacial interaction leads to increased activity in oxidative dehydrogenation of ethanol.
Библиографическая ссылка:
Grabchenko M.V.
, Mamontov G.V.
, Zaikovskii V.I.
, La Parola V.
, Liotta L.F.
, Vodyankina O.V.
Design of Ag-CeO2/SiO2 Catalyst for Oxidative Dehydrogenation of Ethanol: Control of Ag–CeO2 Interfacial Interaction
Catalysis Today. 2019. V.333. P.2-9. DOI: 10.1016/j.cattod.2018.05.014 WOS Scopus РИНЦ OpenAlex CAPlusCA
Design of Ag-CeO2/SiO2 Catalyst for Oxidative Dehydrogenation of Ethanol: Control of Ag–CeO2 Interfacial Interaction
Catalysis Today. 2019. V.333. P.2-9. DOI: 10.1016/j.cattod.2018.05.014 WOS Scopus РИНЦ OpenAlex CAPlusCA
Даты:
| Поступила в редакцию: | 13 дек. 2017 г. |
| Принята к публикации: | 6 мая 2018 г. |
| Опубликована online: | 7 мая 2018 г. |
| Опубликована в печати: | 1 авг. 2019 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:000470828100002 |
| ≡ Scopus: | 2-s2.0-85046752349 |
| ≡ РИНЦ: | 41608832 |
| ≡ OpenAlex: | W2801452384 |
| ≡ Chemical Abstracts: | 2018:964860 |
| ≡ Chemical Abstracts (print): | 171:28486 |