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Novel Eco-Friendly Method for Preparation of Mesoporous Alumina from the Product of Rapid Thermal Treatment of Gibbsite Научная публикация

Журнал Superlattices and Microstructures
ISSN: 0749-6036 , E-ISSN: 1096-3677
Вых. Данные Год: 2018, Том: 120, Страницы: 148-160 Страниц : 13 DOI: 10.1016/j.spmi.2018.05.025
Ключевые слова Boehmite; Rapid thermal treatment; Hydrothermal synthesis; CTA-Product; Flash calcination; Peptization
Авторы Danilevich Vladimir V. 1 , Klimov Oleg V. 1 , Nadeina Ksenia A. 1 , Gerasimov Evgeniy Yu. 1 , Cherepanova Svetlana V. 1 , Vatutina Yuliya V. 1 , Noskov Aleksandr S. 1
Организации
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

Информация о финансировании (1)

1 Федеральное агентство научных организаций России 0303-2016-0010

Реферат: Novel eco-friendly method for preparation of mesoporous alumina from the product of rapid thermal treatment of gibbsite (CTA product) without “reprecipitation” stage is described. Compared with the nitrate-ammonia technology of “reprecipitation” of gibbsite to boehmite and its further calcination to γ-Al2O3, the new method consumed less amount of HNO3 per 1 kg of Al2O3 (by 30 times), while the amount of effluents is twice lower. Effluents do not contain ammonium nitrate, since the preparation of boehmite does not include ammonia. It is shown that the method makes it possible to obtain boehmite with needle-shaped particle morphology. The particle size of boehmite and the textural characteristics of alumina are easily adjusted over a wide range by changing the temperature, aging time or peptizing agent. Thus, the pore volume of alumina may be 0.45–0.95 cm3/g with an average pore diameter of 81–256 Å and SBET = 140–240 m2/g.
Библиографическая ссылка: Danilevich V.V. , Klimov O.V. , Nadeina K.A. , Gerasimov E.Y. , Cherepanova S.V. , Vatutina Y.V. , Noskov A.S.
Novel Eco-Friendly Method for Preparation of Mesoporous Alumina from the Product of Rapid Thermal Treatment of Gibbsite
Superlattices and Microstructures. 2018. V.120. P.148-160. DOI: 10.1016/j.spmi.2018.05.025 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
Поступила в редакцию: 5 мар. 2018 г.
Принята к публикации: 16 мая 2018 г.
Опубликована online: 16 мая 2018 г.
Опубликована в печати: 1 авг. 2018 г.
Идентификаторы БД:
Web of science: WOS:000445713700018
Scopus: 2-s2.0-85048176063
РИНЦ: 35755608
Chemical Abstracts: 2018:1035833
OpenAlex: W2803552845
Цитирование в БД:
БД Цитирований
Web of science 31
Scopus 35
РИНЦ 42
OpenAlex 32
Альметрики: