Formation of Active Structures in Monolith Copper–Manganese Oxide Catalysts for Air-Heating Devices | Sciact - CRIS-система Института катализа

Formation of Active Structures in Monolith Copper–Manganese Oxide Catalysts for Air-Heating Devices Научная публикация

Конференция

III Российский конгресс по катализу «РОСКАТАЛИЗ»
22-26 мая 2017 , Нижний Новгород

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 2018, Том: 59, Номер: 4, Страницы: 532-543 Страниц : 12 DOI: 10.1134/s0023158418040122

Ключевые слова

catalyst, monolith support, butane oxidation, CuO, MnOx

Авторы

Shikina N.V. ¹ , Yashnik S.A. ¹ , Gavrilova A.A. ¹ , Dovlitova L.S. ¹ , Khairulin S.R. ¹ , Kozlova G.S. ² , Ismagilov Z.R. ^1,3

Организации

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2	Center for Collective Use, Federal Research Center for Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences, Kemerovo, 650000 Russia
3	Institute of Coal Chemistry and Chemical Materials Science, Federal Research Center for Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences, Kemerovo, 650000 Russia

Информация о финансировании (1)

Российский фонд фундаментальных исследований

17-43-540747

Impregnation catalysts based on CuO, MnOx, and CuO–MnOx with different Cu/Mn ratios supported on ceramic monoliths of alumina and silica are studied by BET, mercury porosimetry, X-ray diffraction analysis, transmission and scanning electron microscopy, temperature-programmed reduction with H2, diffuse reflectance electron spectroscopy, and differential dissolution. It is found that, in the butane oxidation reaction, CuO–MnOx catalysts exert a synergistic effect, which is attributed to the formation of highly defective phases of complex oxides of the nonstoichiometric spinel type with a large number of interparticle boundaries in the near-surface layers of the support.

Shikina N.V. , Yashnik S.A. , Gavrilova A.A. , Dovlitova L.S. , Khairulin S.R. , Kozlova G.S. , Ismagilov Z.R.
Formation of Active Structures in Monolith Copper–Manganese Oxide Catalysts for Air-Heating Devices
Kinetics and Catalysis. 2018. V.59. N4. P.532-543. DOI: 10.1134/s0023158418040122 WOS Scopus РИНЦ CAPlus OpenAlex

Шикина Н.В. , Яшник С.А. , Гаврилова А.А. , Довлитова Л.С. , Хайрулин С.Р. , Козлова Г.С. , Исмагилов З.Р.
Формирование активных структур в блочных Cu−Mn-оксидных катализаторах для воздухонагревательных устройств
Кинетика и катализ. 2018. Т.59. №4. С.517-528. DOI: 10.1134/S0453881118040123 РИНЦ OpenAlex

Поступила в редакцию:	10 янв. 2018 г.
Опубликована в печати:	1 июл. 2018 г.
Опубликована online:	4 авг. 2018 г.

Web of science:	WOS:000440802700017
Scopus:	2-s2.0-85051136433
РИНЦ:	35721665
Chemical Abstracts:	2018:1445900
OpenAlex:	W2886468883

БД	Цитирований
Web of science	5
Scopus	4
РИНЦ	3
OpenAlex	5