Promoting Effect of 4-Dimethylaminopyridine on Selective Oxidation of Benzyl Alcohol over MoVTeNb Mixed Oxides Full article
| Journal |
Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905 |
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| Output data | Year: 2018, Volume: 117, Pages: 49-52 Pages count : 4 DOI: 10.1016/j.catcom.2018.08.025 | ||||||
| Tags | Multicomponent vanadium-based metal oxides; Selective oxidation; DMAP; Nucleophilic assistance | ||||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0006 (V.44.1.6) |
Abstract:
A liquid phase oxidation of benzyl alcohol with 1 atm molecular oxygen catalyzed by MoVTeNb mixed oxides has been investigated. It is demonstrated that 4-dimethylaminopyridine (DMAP) acting as a co-catalyst, notably accelerates the reaction, as well as influences the ratio of the reaction products (benzaldehyde, benzyl benzoate and benzoic acid). The findings can be interpreted in terms of the involvement of DMAP (a good enough N-nucleophile) in the process of chemo-desorption of oxygenates formed on the catalyst surface.
Cite:
Koltunov K.Y.
, Ishchenko E.V.
, Sobolev V.I.
Promoting Effect of 4-Dimethylaminopyridine on Selective Oxidation of Benzyl Alcohol over MoVTeNb Mixed Oxides
Catalysis Communications. 2018. V.117. P.49-52. DOI: 10.1016/j.catcom.2018.08.025 WOS Scopus РИНЦ ANCAN OpenAlex
Promoting Effect of 4-Dimethylaminopyridine on Selective Oxidation of Benzyl Alcohol over MoVTeNb Mixed Oxides
Catalysis Communications. 2018. V.117. P.49-52. DOI: 10.1016/j.catcom.2018.08.025 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jul 11, 2018 |
| Accepted: | Aug 27, 2018 |
| Published online: | Aug 29, 2018 |
| Published print: | Dec 1, 2018 |
Identifiers:
| Web of science: | WOS:000447480600010 |
| Scopus: | 2-s2.0-85052620092 |
| Elibrary: | 35739342 |
| Chemical Abstracts: | 2018:1656379 |
| Chemical Abstracts (print): | 169:370006 |
| OpenAlex: | W2888944550 |