Hydrogen Production via Steam Reforming of Bio-Oil's Light Components - Ethanol and Glycerol - over Supported Nikelates | Sciact - CRIS-system of Boreskov Institute of Catalysis

Hydrogen Production via Steam Reforming of Bio-Oil's Light Components - Ethanol and Glycerol - over Supported Nikelates Conference Abstracts

Conference

Catalyst Design: 4th International School-Conference on Catalysis for Young Scientists
05-06 Sep 2015 , Казань

Source

CATALYST DESIGN. From Molecular to Industrial level / 4th International School-Conference on Catalysis for Young Scientists (ISCC-2015) (September 5-6, 2015 Kazan, Russia)
Compilation, BIC. Novosibirsk.2015. 218 c. ISBN 9785906376114. РИНЦ

Output data

Year: 2015, Article number : OP-19, Pages count : 2

Authors

Arapova M.V. ^1,3 , Pavlova S.N. ¹ , Parkhomenko K.V. ³ , Glazneva T.S. ^1,2 , Larina T.V. ¹ , Rogov V.A. ^1,2 , Krieger T.A. ¹ , Sadykov V.A. ^1,2 , Roger A.-C. ³

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Pr. Lavrentieva 5, Novosibirsk, 630090, Russia
2	Novosibirsk State University, Ul. Pirogova 2, Novosibirsk, 630090, Russia
3	University of Strasbourg, Strasbourg, France

Funding (3)

1	European Commission	604296 FP7-NMP-2013-LARGE-7 BIOGO
2	Russian Foundation for Basic Research	12-03-93115
3	The Ministry of Education and Science of the Russian Federation

In the present work, the catalysts mLnNi0.9Ru0.1О3/nMg-γ-Al2O3 (Ln = La, Pr, m=10-20%wt, n=6-15%wt) were synthesized and tested in the steam reforming of ethanol (ESR), steam and oxy-steam reforming of glycerol (GSR and GOSR) in a plug-flow reactor at the atmospheric pressure and temperature range of 500-800°C. The study of the catalysts performance in ESR and GSR shows that they provide high values of oxygenates conversion, hydrogen yield and coking stability. The optimal composition of the catalyst with high activity and coking stability has been revealed. It was found that the addition of oxygen in the reaction mixture (GOSR) increases the stability of catalyst to coking, without compromising a high hydrogen yield. The optimal catalyst supported on Ni-Al foam substrate shows a high and stable performance in ESR in a pilot reactor in a realistic reaction mixture during 50 hours

Arapova M.V. , Pavlova S.N. , Parkhomenko K.V. , Glazneva T.S. , Larina T.V. , Rogov V.A. , Krieger T.A. , Sadykov V.A. , Roger A.-C.
Hydrogen Production via Steam Reforming of Bio-Oil's Light Components - Ethanol and Glycerol - over Supported Nikelates
In compilation CATALYST DESIGN. From Molecular to Industrial level / 4th International School-Conference on Catalysis for Young Scientists (ISCC-2015) (September 5-6, 2015 Kazan, Russia). – BIC., 2015. – C.55-56. – ISBN 9785906376114.

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