Preparation of Metal–Polymer Composites through the Thermolysis of Fe(II), Co(II), and Ni(II) Maleates | Sciact - CRIS-система Института катализа

Preparation of Metal–Polymer Composites through the Thermolysis of Fe(II), Co(II), and Ni(II) Maleates Научная публикация

Журнал

Inorganic Materials
ISSN: 0020-1685 , E-ISSN: 1608-3172

Вых. Данные

Год: 2013, Том: 49, Номер: 10, Страницы: 1055-1060 Страниц : 6 DOI: 10.1134/S0020168513100142

Ключевые слова

Polymer Matrix; Thermolysis; Graphene Layer; Polymer Shell; Graphene Shell

Авторы

Yudanova L.I. ¹ , Logvinenko V.A. ¹ , Yudanov N.F. ¹ , Rudina N.A. ² , Ishchenko A.V. ² , Semyannikov P.P. ¹ , Sheludyakova L.A. ¹ , Alferova N.I. ¹ , Romanenko A.I. ¹ , Anikeeva O.B. ¹

Организации

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia
2	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090, Russia

Metal-polymer composites have been prepared through the thermolysis of the [M1(H2O)2(C4H2O4)] · H2O (M1 = Co(II), Ni(II)) neutral maleates and [M2(H2O)4(C4H3O4)2] (M2 = Fe(II), Co(II), Ni(II)) acid maleates. In the polymer matrix of the Fe-containing composite, we identified metal, Fe2O3, and Fe3O4 particles, with slight densification of the matrix around them. The polymer matrix of the cobalt maleate-derived composite contained four types of nanoparticles: α-Co, β-Co, and CoO in polymer shells and Co3O4 with no polymer shell. The decomposition of the nickel maleates yielded homogeneous nickel nanoparticles (4–5 nm) covered with two to five graphene layers. The Co-containing composite was found to be a dielectric. The Ni-containing composite exhibited variable range hopping conduction in the range T ≤ 50 K.

Yudanova L.I. , Logvinenko V.A. , Yudanov N.F. , Rudina N.A. , Ishchenko A.V. , Semyannikov P.P. , Sheludyakova L.A. , Alferova N.I. , Romanenko A.I. , Anikeeva O.B.
Preparation of Metal–Polymer Composites through the Thermolysis of Fe(II), Co(II), and Ni(II) Maleates
Inorganic Materials. 2013. V.49. N10. P.1055-1060. DOI: 10.1134/S0020168513100142 WOS Scopus РИНЦ CAPlusCA OpenAlex

Юданова Л.И. , Логвиненко В.А. , Юданов Н.Ф. , Рудина Н.А. , Ищенко А.В. , Семянников П.П. , Шелудякова Л.А. , Алферова Н.И. , Романенко А.И. , Аникеева О.Б.
Синтез композитов металл/полимер термолизом солей малеиновой кислоты Fe(II), Co(II) и Ni(II)
Неорганические материалы. 2013. Т.49. №10. С.1138-1143. DOI: 10.7868/S0002337X1310014X РИНЦ OpenAlex

Поступила в редакцию:	15 февр. 2013 г.
Опубликована online:	28 авг. 2013 г.
Опубликована в печати:	1 окт. 2013 г.

Web of science:	WOS:000323659500017
Scopus:	2-s2.0-84883738298
РИНЦ:	20450673
Chemical Abstracts:	2013:1550196
Chemical Abstracts (print):	160:311522
OpenAlex:	W1981716612

БД	Цитирований
Web of science	19
Scopus	23
РИНЦ	21
OpenAlex	24