Ethanol Conversion into Chemicals over Au-M Containing Catalysts | Sciact - CRIS-система Института катализа

Ethanol Conversion into Chemicals over Au-M Containing Catalysts Тезисы доклада

Конференция

EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 авг. - 4 сент. 2015 , Казань

Сборник

EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts
Сборник, BIC SB RAS. Novosibirsk.2015. 2184 c. ISBN 978-5-906376-10-7. РИНЦ

Вых. Данные

Год: 2015, Страницы: 89-90 Страниц : 2

Авторы

Chistyakov A.V. ^1,2 , Nikolaev S.A. ³ , Zharova P.A. ¹ , Kriventsov V.V. ⁴ , Tsodikov M.V. ^1,2

Организации

1	Topchuev Institute of Petrochemical Synthesis RAS, Moscow, Russia
2	Gubkin Russian State University of Oil and Gas, Moscow, Russia
3	Lomonosov Moscow State University, Moscow, Russia
4	Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia

Информация о финансировании (3)

1	Российский фонд фундаментальных исследований	13-03-12034 (01201367680)
2	Российский фонд фундаментальных исследований	15-03-06479
3	Совет по грантам Президента Российской Федерации	МК-5328.2014.3

Direct catalytic valorization of ethanol either to olefins fractions C3-C8 or 1-butanol, 1-hexanol and 1-octanol over Au-Cu and Au-Ni containing catalysts was studied. Selectivity of 1-butanol formation was 75 %. First time ever over heterogeneous catalysts the reaction of ethanol and iso-propanol was carried on resulted in 3-methyl-2-butanol formation that is precursor of valuable monomer – isoprene. The peculiarities of the reaction mechanism are discussed, with the specific surface and electronic features of the prepared catalysts being considered. Found that growing the Au particles by forming the mixed MO/Au (M- Cu, Ni) particles resulted in an increased aim products selectivity

Chistyakov A.V. , Nikolaev S.A. , Zharova P.A. , Kriventsov V.V. , Tsodikov M.V.
Ethanol Conversion into Chemicals over Au-M Containing Catalysts
В сборнике EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – BIC SB RAS., 2015. – C.89-90. – ISBN 978-5-906376-10-7.

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