Oxidation of n-Heptane over Sphere Catalysts with a Composition of TiO2-SiO2-MxOy, where M is Со or Ni | Sciact - CRIS-система Института катализа

Oxidation of n-Heptane over Sphere Catalysts with a Composition of TiO2-SiO2-MxOy, where M is Со or Ni Тезисы доклада

Конференция

EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 авг. - 4 сент. 2015 , Казань

Сборник

EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts
Сборник, BIC SB RAS. Novosibirsk.2015. 2184 c. ISBN 978-5-906376-10-7. РИНЦ

Вых. Данные

Год: 2015, Страницы: 575-576 Страниц : 2

Авторы

Shamsutdinova A. ¹ , Zharkova V. ¹ , Brichkov A. ¹ , Glazneva T. ² , Bobkova L. ¹ , Larina T. ² , Paukshtis E. ^1,2 , Parmon V. ^1,2 , Kozik V. ¹

Организации

1	National Research Tomsk State University, Tomsk, Russia
2	Boreskov institute of catalysis SB RAN, Novosibirsk, Russia

Информация о финансировании (1)

Министерство образования и науки Российской Федерации

11.801.2014/K

The preparation technique of new composite catalytic materials in the form of hollow spheres was developed. TiO2-SiO2 composites were modified by nickel and cobalt. After annealing, the spatial structure of sphere samples was studied by X-ray microtomography on a digital 3D microtomograph. The state of the cations of transition elements and titanium was characterized by UV-Vis DR spectroscopy. The catalysts were tested in the oxidation of n-heptane. It was found that besides the destructive oxidation, the oxidative dehydrogenation of n-heptane and formation of partial oxidation products such as ketones and esters took place. The selectivity towards the partial oxidation products at 400-450oC reaches 63% on Ni modified catalyst

Shamsutdinova A. , Zharkova V. , Brichkov A. , Glazneva T. , Bobkova L. , Larina T. , Paukshtis E. , Parmon V. , Kozik V.
Oxidation of n-Heptane over Sphere Catalysts with a Composition of TiO2-SiO2-MxOy, where M is Со or Ni
В сборнике EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – BIC SB RAS., 2015. – C.575-576. – ISBN 978-5-906376-10-7.

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