Study of Influence of cis-trans Isomerization on Selective Oxidations of Alkenes by Nitrous Oxide | Sciact - CRIS-system of Boreskov Institute of Catalysis

Study of Influence of cis-trans Isomerization on Selective Oxidations of Alkenes by Nitrous Oxide Conference Abstracts

Conference

EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 Aug - 4 Sep 2015 , Казань

Source

EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts
Compilation, BIC SB RAS. Novosibirsk.2015. 2184 c. ISBN 978-5-906376-10-7. РИНЦ

Output data

Year: 2015, Pages: 156-157 Pages count : 2

Authors

Ivanov D.P. ¹ , Semikolenov S.V. ¹ , Nartova A.V. ^1,2 , Fedorov V.S. ^1,2 , Babushkin D.E. ¹ , Dubkov K.A. ¹

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia

Funding (1)

Russian Foundation for Basic Research

14-03-31052

In the present work the influence of cis-trans isomerization of heptane-3 on reactivity of C=C bond of alkenes towards N2O as well as the contribution of the reaction route with the break of the initial double bounds were studied. It was shown that both cis- and trans-heptane isomers perform very similar reactivity. At the same time for trans-hepten-3 the contribution of the route with C-C bound break is approximately three times higher comparing with cis-heptane-3. The study reveals the common regularities of the oxidation of compounds with C=C bounds by nitrous oxide. The observed difference in contribution of the reaction route with C-C bound break for the olefins confirms the results obtained for rubbers previously.

Ivanov D.P. , Semikolenov S.V. , Nartova A.V. , Fedorov V.S. , Babushkin D.E. , Dubkov K.A.
Study of Influence of cis-trans Isomerization on Selective Oxidations of Alkenes by Nitrous Oxide
In compilation EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – BIC SB RAS., 2015. – C.156-157. – ISBN 978-5-906376-10-7.

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