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Solvation Shell of Platinum Complexes in Solutions According to EXAFS Data Conference Abstracts

Conference EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources”
30 Aug - 4 Sep 2015 , Казань
Source EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts
Compilation, BIC SB RAS. Novosibirsk.2015. 2184 c. ISBN 978-5-906376-10-7. РИНЦ
Output data Year: 2015, Pages: 457-458 Pages count : 2
Authors Kanazhevskiy V. 1 , Chesalov Yu. 1 , Kochubey D. 1
Affiliations
1 Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia

Abstract: Using EXAFS and vibrational spectroscopy a tightly bound solvation shell of H2PtCl6 in DMSO and water solutions is established. The shell contains H3O+, H5O2+ and DMSO molecules, depending on the solvent type. EXAFS suggests O-atoms of the shell are located at a distance of 3.7-4.4 Å from Pt. Complexes' structure was studied in wide concentration range DMSO and water solutions. The complexes are mononuclear and unhydrolyzed. Combining via the shell is possible
Cite: Kanazhevskiy V. , Chesalov Y. , Kochubey D.
Solvation Shell of Platinum Complexes in Solutions According to EXAFS Data
In compilation EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts. – BIC SB RAS., 2015. – C.457-458. – ISBN 978-5-906376-10-7.
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