Copper-Cerium Oxide Catalysts Supported on Monoclinic Zirconia: Structural Features and Catalytic Behavior in Preferential Oxidation of Carbon Monoxide in Hydrogen Excess | Sciact - CRIS-system of Boreskov Institute of Catalysis

Copper-Cerium Oxide Catalysts Supported on Monoclinic Zirconia: Structural Features and Catalytic Behavior in Preferential Oxidation of Carbon Monoxide in Hydrogen Excess Full article

Journal

Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875

Output data

Year: 2009, Volume: 365, Number: 2, Pages: 159-164 Pages count : 5 DOI: 10.1016/j.apcata.2009.06.001

Tags

CeO2, Copper oxide clusters, Preferential CO oxidation, Structure-activity relation, XAFS, ZrO2

Authors

Pakharukova Vera P. ¹ , Moroz Ella M. ¹ , Kriventsov Vladimir V. ¹ , Zyuzin Dmitry A. ¹ , Kosmambetova Gulnara R. ² , Strizhak Peter E. ²

Affiliations

1	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Pr. Lavrentieva, 5, Novosibirsk 630090, Russia
2	Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Pr. Nauki, 31, Kiev 03039, Ukraine

Funding (1)

Russian Foundation for Basic Research

09-03-90424

Copper–cerium oxide catalysts supported on monoclinic zirconia CuO/CeO2/ZrO2 were tested in the preferential oxidation of CO in hydrogen-rich gases and the optimal catalyst composition was determined. The state and the structure of copper species in the catalysts were investigated by X-ray diffraction (XRD) and X-ray absorption fine structure (XAFS) analysis. While a small amount of copper incorporated into the surface layers of the CeO2 lattice, the disordered oxide clusters were the main copper species in the catalysts with copper content ≤5 wt.%. The increase in the copper loading (>10 wt.%) led to predominant formation of bulk CuO phase coupled with catalyst deactivation.

Pakharukova V.P. , Moroz E.M. , Kriventsov V.V. , Zyuzin D.A. , Kosmambetova G.R. , Strizhak P.E.
Copper-Cerium Oxide Catalysts Supported on Monoclinic Zirconia: Structural Features and Catalytic Behavior in Preferential Oxidation of Carbon Monoxide in Hydrogen Excess
Applied Catalysis A: General. 2009. V.365. N2. P.159-164. DOI: 10.1016/j.apcata.2009.06.001 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Apr 9, 2009
Accepted:	Jun 1, 2009
Published online:	Jun 8, 2009
Published print:	Aug 31, 2009

Web of science:	WOS:000269653000003
Scopus:	2-s2.0-67749108214
Elibrary:	13600178
Chemical Abstracts:	2009:930618
Chemical Abstracts (print):	151:432012
OpenAlex:	W2105041204

DB	Citing
Web of science	38
Scopus	39
Elibrary	41
OpenAlex	43