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Bi(III) Immobilization Inside MIL-101: Enhanced Photocatalytic Performance Full article

Journal New Journal of Chemistry
ISSN: 1144-0546 , E-ISSN: 1369-9261
Output data Year: 2017, Volume: 41, Number: 6, Pages: 2255-2260 Pages count : 6 DOI: 10.1039/c6nj03482a
Tags METAL-ORGANIC FRAMEWORKS; VISIBLE-LIGHT; HETEROGENEOUS CATALYSTS; DYE DEGRADATION; WATER-TREATMENT; BIOX X; COMPOSITE; NANOPARTICLES; COMPLEXES; LIGAND
Authors Kovalenko Konstantin A. 1,2 , Ruban Natalia V. 2 , Adonin Sergey A. 1,2 , Korneev Denis V. 3 , Erenburg Simon B. 1,4 , Trubina Svetlana V. 1 , Kvashnina Kristina 5,6 , Sokolov Maxim N. 1,7 , Fedin Vladimir P. 1,2
Affiliations
1 Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Akad. Lavrentiev Av., 630090 Novosibirsk, Russian Federation
2 Novosibirsk State University, 2 Pirogova Street, 630090 Novosibirsk, Russian Federation
3 State Research Centre for Virology and Biotechnology ‘‘Vector’’, 630559 Koltsovo, Novosibirsk Region, Russian Federation
4 Budker Institute of Nuclear Physics SB RAS, 11 Akad. Lavrentiev Av., 630090 Novosibirsk, Russian Federation
5 European Synchrotron Radiation Facility, BP 220, 38043, Grenoble Cedex, France
6 Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Institute of Resource Ecology, P.O. Box 510119, 01314, Dresden, Germany
7 Kazan Federal University, Alexander Butlerov Institute of Chemistry, Lobachevskogo Street 1/29, 420008, Kazan, Russian Federation

Funding (1)

1 Russian Science Foundation 14-23-00013 (116011510036)

Abstract: A novel hybrid material Bi(III)@MIL-101 (Bi(III) = Bi-containing oxoclusters and MIL-101 = chromium(III) oxoterephthalate) was obtained by the intra-pore hydrolysis of guest bismuth(III) chloride in ammonia solution. This compound was characterized by chemical analysis, powder X-ray diffraction, nitrogen sorption and TEM techniques. According to the obtained data all Bi species are located only inside the matrix. The framework structure remains intact during all synthetic operations. The chemical nature of Bi(III)-containing clusters inside the MIL-101 matrix was suggested based on the EXAFS study. The catalytic activity of Bi(III)@MIL-101 in photodegradation of methyl red (MR) has been tested. The introduction of Bi(III)-species inside MIL-101 significantly increases the photocatalytic performance in comparison with layered BiOCl which was obtained under the same synthetic conditions without MIL-101.
Cite: Kovalenko K.A. , Ruban N.V. , Adonin S.A. , Korneev D.V. , Erenburg S.B. , Trubina S.V. , Kvashnina K. , Sokolov M.N. , Fedin V.P.
Bi(III) Immobilization Inside MIL-101: Enhanced Photocatalytic Performance
New Journal of Chemistry. 2017. V.41. N6. P.2255-2260. DOI: 10.1039/c6nj03482a WOS Scopus РИНЦ ANCAN OpenAlex
Files: Full text from publisher
Dates:
Submitted: Nov 7, 2016
Accepted: Jan 30, 2017
Published online: Jan 31, 2017
Published print: Mar 21, 2017
Identifiers:
Web of science: WOS:000397749000008
Scopus: 2-s2.0-85015386555
Elibrary: 29490355
Chemical Abstracts: 2017:180275
Chemical Abstracts (print): 166:290932
OpenAlex: W2582139779
Citing:
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Web of science 7
Scopus 8
OpenAlex 8
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