Effects Arising from the Replacement of Aprotic Dipolar Solvents with Ionic Liquids in the Nickel-Catalyzed Reduction of Aryl Chlorides Full article
| Journal |
Molecular Catalysis
ISSN: 2468-8231 |
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| Output data | Year: 2018, Volume: 461, Pages: 19-25 Pages count : 7 DOI: 10.1016/j.mcat.2018.09.022 | ||||
| Tags | Homocoupling, Hydrodehalogenation, Aryl chlorides, Ionic liquid, Zinc, Nickel complexes | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0007 |
Abstract:
In the work on the example of liquid-phase catalytic processes of the aromatic CCl bonds activation occurring in the presence of nickel complexes under reducing conditions the main effects arising from the replacement of aprotic dipolar solvents with ionic liquids are analyzed. The features of the nickel-catalyzed reaction of aryl chlorides, related to the nature of the anion and cation of the ionic liquid, were observed. It was shown that a high concentration of cations and anions in the ionic liquid affects the process of reduction of the nickel complex to the catalytically active state. In addition, the presence of a reactive hydrogen atom in the imidazolium cation of ionic liquid causes the process of hydrodechlorination of aryl chlorides.
Cite:
Prikhod’ko S.A.
, Popov A.G.
, Adonin N.Y.
Effects Arising from the Replacement of Aprotic Dipolar Solvents with Ionic Liquids in the Nickel-Catalyzed Reduction of Aryl Chlorides
Molecular Catalysis. 2018. V.461. P.19-25. DOI: 10.1016/j.mcat.2018.09.022 WOS Scopus РИНЦ OpenAlex ANCAN
Effects Arising from the Replacement of Aprotic Dipolar Solvents with Ionic Liquids in the Nickel-Catalyzed Reduction of Aryl Chlorides
Molecular Catalysis. 2018. V.461. P.19-25. DOI: 10.1016/j.mcat.2018.09.022 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Jun 28, 2018 |
| Accepted: | Sep 30, 2018 |
| Published online: | Oct 10, 2018 |
| Published print: | Dec 1, 2018 |
Identifiers:
| ≡ Web of science: | WOS:000450383700003 |
| ≡ Scopus: | 2-s2.0-85054458060 |
| ≡ Elibrary: | 38618358 |
| ≡ OpenAlex: | W2898042497 |
| ≡ Chemical Abstracts: | 2019:573415 |
| ≡ Chemical Abstracts (print): | 170:477382 |