Studying the Effect of Magnesium on the Activity of a Deep Oxidation Catalyst for a Fluidized Bed in Methane and CO Oxidation Reactions Full article
| Journal |
Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555 |
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| Output data | Year: 2018, Volume: 10, Number: 3, Pages: 237-243 Pages count : 7 DOI: 10.1134/S2070050418030030 | ||
| Tags | catalysts, deep oxidation, methane, CO, fluidized bed, flow-circulating mode | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 17-73-30032 |
Abstract:
A comparative study is performed on the activity of industrial and laboratory samples of
CuO/Al2O3, MgO-Cr2O3/Al2O3, CuO-Cr2O3/Al2O3, and CuO/Al2O3MgO-Cr2O3 catalysts under fluidized
bed conditions in model CO and CH4 oxidation reactions. For the combustion of gaseous fuels and gas mixtures
(including low-percentage methane mixtures), aluminum–copper–magnesium–chromium catalysts
are found to be the ones most promising. Studying their activity in the model reaction of methane oxidation
while varying the content of magnesium in the composition of this catalytic system shows that the optimum
magnesium content lies in the range of 1–2 wt %. The metals on the surfaces of these samples are found to be
in the most stable states: Cu2+, Cr3+, Mg2+, and Al3+. The composition and textural and strength characteristics
of the samples are studied by physicochemical means (BET, XPS, XRD, and X-ray fluorescence analysis).
Cite:
Dubinin Y.V.
, Tsereshko N.A.
, Saraev A.A.
, Bulavchenko O.A.
, Yakovlev V.A.
Studying the Effect of Magnesium on the Activity of a Deep Oxidation Catalyst for a Fluidized Bed in Methane and CO Oxidation Reactions
Catalysis in Industry. 2018. V.10. N3. P.237-243. DOI: 10.1134/S2070050418030030 WOS Scopus РИНЦ OpenAlex
Studying the Effect of Magnesium on the Activity of a Deep Oxidation Catalyst for a Fluidized Bed in Methane and CO Oxidation Reactions
Catalysis in Industry. 2018. V.10. N3. P.237-243. DOI: 10.1134/S2070050418030030 WOS Scopus РИНЦ OpenAlex
Original:
Дубинин Ю.В.
, Церешко Н.А.
, Сараев А.А.
, Булавченко О.А.
, Яковлев В.А.
Исследование влияния магния на активность катализаторов глубокого окисления для кипящего слоя в реакциях окисления CH4 и CO
Катализ в промышленности. 2018. Т.18. №1. С.51-59. DOI: 10.18412/1816-0387-2018-1-51-59 РИНЦ AN OpenAlex
Исследование влияния магния на активность катализаторов глубокого окисления для кипящего слоя в реакциях окисления CH4 и CO
Катализ в промышленности. 2018. Т.18. №1. С.51-59. DOI: 10.18412/1816-0387-2018-1-51-59 РИНЦ AN OpenAlex
Dates:
| Submitted: | Nov 7, 2017 |
| Published print: | Jul 1, 2018 |
| Published online: | Oct 9, 2018 |
Identifiers:
| Web of science: | WOS:000446835400007 |
| Scopus: | 2-s2.0-85054845447 |
| Elibrary: | 38641871 |
| OpenAlex: | W2897731113 |