Interaction of Vanadium Containing Catalysts with Microwaves and Their Activation in Oxidative Dehydrogenation of Ethane Full article
| Conference |
8th European Workshop Meeting on Selective Oxidation 26-31 Aug 2007 , Turku |
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| Journal |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
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| Output data | Year: 2009, Volume: 141, Number: 3-4, Pages: 300-305 Pages count : 6 DOI: 10.1016/j.cattod.2008.04.021 | ||||||
| Tags | Antimony, Catalyst, Dehydrogenation, Ethane, Microwave activation, Molybdenum, Niobium, Vanadium | ||||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Haldor Topsoe A/S |
Abstract:
Microwave (MW)-activated oxidative dehydrogenation of ethane is studied using kinetic approach. It consists in the comparison of kinetic dependencies (shape of kinetic equations, “selectivity or yield vs. conversion” curves) and apparent parameters (activation energies) obtained in thermal and MW modes. In the case of VMo and VMoNb oxides a distinct difference between ethane yields was observed at given conversion of limiting reactant (oxygen). It was proven by X-ray diffraction that MW activation changes the catalyst microstructure forming phase distribution different from that formed under a conventional heating and thus changing catalytic behavior of VMo and VMoNb oxides.
Cite:
Sinev I.
, Kardash T.
, Kramareva N.
, Sinev M.
, Tkachenko O.
, Kucherov A.
, Kustov L.M.
Interaction of Vanadium Containing Catalysts with Microwaves and Their Activation in Oxidative Dehydrogenation of Ethane
Catalysis Today. 2009. V.141. N3-4. P.300-305. DOI: 10.1016/j.cattod.2008.04.021 WOS Scopus РИНЦ ANCAN OpenAlex
Interaction of Vanadium Containing Catalysts with Microwaves and Their Activation in Oxidative Dehydrogenation of Ethane
Catalysis Today. 2009. V.141. N3-4. P.300-305. DOI: 10.1016/j.cattod.2008.04.021 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Published online: | Jun 16, 2008 |
| Published print: | Mar 30, 2009 |
Identifiers:
| Web of science: | WOS:000264816500010 |
| Scopus: | 2-s2.0-60949106658 |
| Elibrary: | 13600616 |
| Chemical Abstracts: | 2009:252040 |
| Chemical Abstracts (print): | 150:473183 |
| OpenAlex: | W2032088186 |