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Analysis of the Facilities of the NMR in Study of the Geometry of Paramagnetic Metal Complexes in Solutions Conference Abstracts

Conference XXth Congress AMPERE
21-26 Aug 1978 , Tallinn
Source Magnetic Resonance and Related Phenomena: Proceedings of the XXth Congress AMPERE, Tallinn, August 21–26, 1978
Compilation, Springer. Berlin, Heidelberg.1979. 606 c. ISBN 9783642813467;9783642813443.
Output data Year: 1979, Pages: 503-503 Pages count : 1 DOI: 10.1007/978-3-642-81344-3_439
Tags Paramagnetic Shift; Base Heterocycle; Artificial Error;Isotropic Complex; Density Delocalization
Authors Nekipelov V.M. 1 , Zamaraev K.I. 1
Affiliations
1 Institute of Catalysis of the Siberian Branch of the Academy of Sciences of the USSR, Novosibirsk, USSR

Abstract: Using complexes of bisacetylacetonato Co(II) and Ni(II) with pyridine type ligands as models, it was shown that geometric parameters of paramagnetic metal complexes may be calculated using a set of equations, left parts of which are experimental NMR data (chemical shifts and relaxation rates) and right ones — theoretical expressions for them. The validity of the proposed procedure is confirmed by the existence of solutions for sets with the number of equations exceeding the number of the unknown parameters as well as by a rather good accuracy (about 5%) of the calculated values and their good agreement with the corresponding X-ray data.
Cite: Nekipelov V.M. , Zamaraev K.I.
Analysis of the Facilities of the NMR in Study of the Geometry of Paramagnetic Metal Complexes in Solutions
In compilation Magnetic Resonance and Related Phenomena: Proceedings of the XXth Congress AMPERE, Tallinn, August 21–26, 1978. – Springer., 1979. – C.503-503. – ISBN 9783642813467;9783642813443. DOI: 10.1007/978-3-642-81344-3_439ANCAN OpenAlex
Identifiers:
Chemical Abstracts: 1980:523201
Chemical Abstracts (print): 93:123201
OpenAlex: W2485140575
Citing: Пока нет цитирований
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