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Effect of Citric Acid and Triethylene Glycol Addition on the Reactivation of CoMo/γ-Al2O3 Hydrotreating Catalysts Full article

Conference III Scientific-Technological Symposium "Catalytic Hydroprocessing in Oil Refining"
16-20 Apr 2018 , Lyon
Journal Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308
Output data Year: 2019, Volume: 329, Pages: 35-43 Pages count : 9 DOI: 10.1016/j.cattod.2018.10.017
Tags Calcination Citric acid Cobalt compounds Fourier transform infrared spectroscopy Glycols Molybdenum compounds Sulfur compounds
Authors Budukva S.V. 1 , Klimov O.V. 1 , Uvarkina D.D. 1 , Chesalov Yu.A. 1 , Prosvirin I.P. 1 , Larina T.V. 1 , Noskov A.S. 1
Affiliations
1 Boreskov Institute of Catalysis SB RAS, 5, pr. Lavrentieva, 630090 Novosibirsk, Russia

Funding (1)

1 Federal Agency for Scientific Organizations 0303-2016-0010

Abstract: Calcined CoMo/γ-Al2O3 hydrotreating catalysts were reactivated by a solution of citric acid and triethylene glycol. The reactivated catalysts were tested in HDS of dibenzothiophene and hydrotreating of SRGO. The reactivated catalysts were showed a significant increase in activity compared to calcined. The highest reactivation was observed for the sample reactivated using a solution of citric acid and triethylene glycol. All catalysts were characterized by means of UV-DRS, FTIR, Raman spectroscopy, XRD, XPS, and HTREM. It has been shown that the addition of triethylene glycol increases the proportion of CoMoS phase and the dispersion of sulfide particles.
Cite: Budukva S.V. , Klimov O.V. , Uvarkina D.D. , Chesalov Y.A. , Prosvirin I.P. , Larina T.V. , Noskov A.S.
Effect of Citric Acid and Triethylene Glycol Addition on the Reactivation of CoMo/γ-Al2O3 Hydrotreating Catalysts
Catalysis Today. 2019. V.329. P.35-43. DOI: 10.1016/j.cattod.2018.10.017 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Jul 22, 2018
Accepted: Oct 10, 2018
Published online: Oct 22, 2018
Published print: Jun 1, 2019
Identifiers:
Web of science: WOS:000462764600005
Scopus: 2-s2.0-85055516195
Elibrary: 38621184
Chemical Abstracts: 2018:2019464
Chemical Abstracts (print): 170:403693
OpenAlex: W2896584668
Citing:
DB Citing
Scopus 13
Web of science 11
Elibrary 14
OpenAlex 13
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