High Pressure: A Complementary Tool for Probing Solid-State Processes | Sciact - CRIS-система Института катализа

High Pressure: A Complementary Tool for Probing Solid-State Processes Обзор

Журнал

CrystEngComm
ISSN: 1466-8033

Вых. Данные

Год: 2019, Том: 21, Страницы: 10-22 Страниц : 13 DOI: 10.1039/c8ce01391h

Ключевые слова

X-RAY-DIFFRACTION; III AMMINE COMPLEXES; INDUCED STRUCTURAL-CHANGES; DOT-H INTERACTIONS; EQUATION-OF-STATE; CRYSTAL-STRUCTURE; SINGLE-CRYSTAL; PHASE-TRANSITION; HYDROSTATIC-PRESSURE; MOLECULAR-CRYSTALS

Авторы

Zakharov Boris A. ^1,2,3 , Boldyreva Elena V. ^1,2

Организации

1	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentiev Ave. 5, Novosibirsk, Russian Federation
2	Novosibirsk State University, Pirogova Str. 2, Novosibirsk, Russian Federation
3	Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences, Kutateladze Str. 18, Novosibirsk, Russian Federation

Информация о финансировании (2)

1	Российский фонд фундаментальных исследований	16-33-60093 (АААА-А16-116021550279-5)
2	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)

Since the early days of X-ray diffraction, researchers have tried to follow the evolution of crystal structures under extremes of pressure. Recently, interest in this area has exploded, attracting scientists from backgrounds across the physical and life sciences. Much of this rapid expansion has been due to the enhancement of diffraction equipment, including detectors, goniometers, and high-pressure cells, and the development of synchrotron radiation and neutron sources. The high-pressure research generally focuses on the direct effects of pressure on the structural evolution of a system. The present contribution describes examples of a less common application: hydrostatic compression of crystals of organic and coordination compounds can be used as a complementary tool in order to rationalise the mechanisms of the transformations in these solids that take place at atmospheric pressure. The data on the compressibility, equations of state, phase changes, or the effects of pressure on intermolecular distances, molecular conformations and chemical bonds can shed light on the factors that are important for thermal and photochemical reactions in the same crystals without an external load as well as on their solid-state or solvent-assisted polymorphic transformations. The manuscript also discusses how structural studies under extreme conditions can help to rationalise the thermo- and photosalient effects that accompany some solid-state transformations. This knowledge is currently of great importance for materials science since mechanically responsive materials have the potential to be used for the design and manufacture of new supramolecular devices.

Zakharov B.A. , Boldyreva E.V.
High Pressure: A Complementary Tool for Probing Solid-State Processes
CrystEngComm. 2019. V.21. P.10-22. DOI: 10.1039/c8ce01391h WOS Scopus РИНЦ CAPlus OpenAlex

Поступила в редакцию:	18 авг. 2018 г.
Принята к публикации:	16 окт. 2018 г.
Опубликована online:	17 окт. 2018 г.
Опубликована в печати:	7 янв. 2019 г.

Web of science:	WOS:000453688500001
Scopus:	2-s2.0-85058837281
РИНЦ:	38633950
Chemical Abstracts:	2018:1926963
OpenAlex:	W2897781230

БД	Цитирований
Scopus	65
Web of science	61
РИНЦ	63
OpenAlex	67