Ag-Based Catalysts in Heterogeneous Selective Oxidation of Alcohols: A Review | Sciact - CRIS-system of Boreskov Institute of Catalysis

Ag-Based Catalysts in Heterogeneous Selective Oxidation of Alcohols: A Review Review

Journal

Catalysts
ISSN: 2073-4344

Output data

Year: 2018, Volume: 8, Number: 10, Article number : 447, Pages count : 56 DOI: 10.3390/catal8100447

Tags

heterogeneous catalysis; selective oxidation of alcohols; mono- and polyalcohols; silver catalyst; Ag nanoparticles; gas-phase and liquid-phase oxidation of alcohols; photooxidation

Authors

Torbina Viktoriia V. ¹ , Vodyankin Andrei A. ¹ , Ten Sergey ¹ , Mamontov Grigory V. ¹ , Salaev Mikhail A. ¹ , Sobolev Vladimir I. ² , Vodyankina Olga V. ¹

Affiliations

1	Laboratory of catalytic research, Tomsk State University, 36, Lenin Ave., Tomsk 634050, Russia
2	Boreskov Institute of Catalysis, Russian Academy of Sciences, Pr. Akademika Lavrentieva, 5, Novosibirsk 630090, Russia

Funding (1)

The Ministry of Education and Science of the Russian Federation

8.2.03.2018

Alcohols (bioalcohols) is a class of chemicals that are used as a feedstock for the manufacturing of a large number of valuable intermediates in industrially important processes. Currently, sustainable technologies for selective conversion of alcohols utilize “green” oxidants, mainly, ambient air or oxygen. Due to the high affinity of oxygen towards silver, the latter serves as an active component of supported heterogeneous catalysts. In this review, we consider Ag-based catalysts that participate in gas- or liquid-phase oxidation of alcohols. Oxidation of methanol, ethanol, ethylene glycol, propylene glycol, glycerol, benzyl and allyl alcohols is mostly considered. A particular attention is paid to selective photooxidation of alcohols over Ag-based catalysts. We discuss the catalyst composition in terms of (1) the state of the active component, (2) the nature of the substrate, (3) support nature, and (4) the strength of the metal–support interactions.

Torbina V.V. , Vodyankin A.A. , Ten S. , Mamontov G.V. , Salaev M.A. , Sobolev V.I. , Vodyankina O.V.
Ag-Based Catalysts in Heterogeneous Selective Oxidation of Alcohols: A Review

Catalysts. 2018. V.8. N10. 447 :1-56. DOI: 10.3390/catal8100447 WOS Scopus РИНЦ AN OpenAlex

Full text from publisher

Submitted:	Sep 16, 2018
Accepted:	Oct 8, 2018
Published print:	Oct 11, 2018
Published online:	Oct 11, 2018

Web of science:	WOS:000448543300043
Scopus:	2-s2.0-85055716522
Elibrary:	38638191
Chemical Abstracts:	2018:2070648
OpenAlex:	W2897896866

DB	Citing
Scopus	74
Web of science	69
Elibrary	66
OpenAlex	76