Реферат: Catalysts with high nickel concentrations 75%Ni–12%Cu/Al2O3, 70%Ni–10%Cu–10%Fe/Al2O3 were prepared by mechanochemical activation and their catalytic properties were studied in methane decomposition. It was shown that modification of the 75%Ni–12%Cu/Al2O3 catalyst with iron made it possible to increase optimal operating temperatures to 700–750 °C while maintaining excellent catalyst stability. The formation of finely dispersed Ni–Cu–Fe alloy particles makes the catalysts stable and capable of operating at 700–750 °C in methane decomposition to hydrogen and carbon nanofibers. The yield of carbon nanofibers on the modified 70%Ni–10%Cu–10%Fe/Al2O3 catalyst at 700–750 °C was 150–160 g/g. The developed hydrogen production method is also efficient when natural gas is used as the feedstock. An installation with a rotating reactor was developed for production of hydrogen and carbon nanofibers from natural gas. It was shown that the 70%Ni–10%Cu–10%Fe/Al2O3 catalyst could operate in this installation for a prolonged period of time. The hydrogen concentration at the reactor outlet exceeded 70 mol%.

Библиографическая ссылка: Chesnokov V.V. , Chichkan A.S.
Production of Hydrogen by Methane Catalytic Decomposition over Ni-Cu-Fe/Al2O3 Catalyst
International Journal of Hydrogen Energy. 2009. V.34. N7. P.2979-2985. DOI: 10.1016/j.ijhydene.2009.01.074 WOS Scopus РИНЦ CAPlusCA OpenAlex

Даты:

Поступила в редакцию:	10 дек. 2008 г.
Принята к публикации:	27 янв. 2009 г.
Опубликована online:	24 февр. 2009 г.
Опубликована в печати:	1 апр. 2009 г.

Идентификаторы БД:

Web of science:	WOS:000265473900015
Scopus:	2-s2.0-62849111653
РИНЦ:	13614918
Chemical Abstracts:	2009:373753
Chemical Abstracts (print):	152:149197
OpenAlex:	W1967353780

Цитирование в БД:

БД	Цитирований
Web of science	103
Scopus	108
РИНЦ	104
OpenAlex	116

Альметрики: