Structured Catalyst Supports and Catalysts for the Methane Indirect Internal Steam Reforming in the Intermediate Temperature SOFC | Sciact - CRIS-система Института катализа

Structured Catalyst Supports and Catalysts for the Methane Indirect Internal Steam Reforming in the Intermediate Temperature SOFC Научная публикация

Журнал

International Journal of Heat and Mass Transfer
ISSN: 0017-9310

Вых. Данные

Год: 2009, Том: 34, Номер: 23, Страницы: 9505-9514 Страниц : 10 DOI: 10.1016/j.ijhydene.2009.09.079

Ключевые слова

Catalysis; Catalyst deactivation; Catalyst poisoning; Cerium; Cerium compounds; Chromium; Foams; Manganese; Manganese compounds; Metals; Methane; Nickel; Oxide minerals; Oxygen; Perovskite; Platinum; Platinum compounds; Steam engineering; Zirconium

Авторы

Smorygo Oleg ¹ , Mikutski Vitali ¹ , Marukovich Alexander ¹ , Vialiuha Yuri ¹ , Ilyushchanka Alexander ¹ , Mezentseva Natalia ² , Alikina Galina ² , Vostrikov Zakhar ² , Fedorova Yulia ² , Pelipenko Vladimir ² , Bunina Rimma ² , Sadykov Vladislav ²

Организации

1	Powder Metallurgy Institute, 41 Platonov str., Minsk 220005, Belarus
2	Boreskov Institute of Catalysis, pr. Lavrentieva, 5, Novosibirsk 630090, Russia

Информация о финансировании (2)

1	European Commission	20089 FP6-2004-ENERGY-3 SOFC600
2	Национальная академия наук Беларуси	T09CO-003

Open cell metal foams made from Ni, Fe–Cr steel and Ni–Al intermetallic were studied as candidate catalyst supports for the internal indirect methane steam reforming. All the samples exhibited good corrosive resistance during 500–1000 h testing in H2–H2O–Ar environment at 600 °C. NiO/8YSZ composite based catalysts doped with fluorite-like (Pr0.3Ce0.35Zr0.35O2) or perovskite-like (La0.8Pr0.2Mn0.2Cr0.8O3) complex oxides with high lattice oxygen mobility and promoted with Pt or Ru were prepared and deposited on the foam-structure supports. Both good catalyst adhesion and stable catalyst performance were achieved in the case of the Ni–Al foam supported catalysts. The Fe–Cr support reacted with the catalytic active components resulting in fast catalyst deactivation. The foam supported catalyst performance was compared with the same catalyst prepared in a form of 0.25 mm fraction. Porous supports with different porosities were prepared by the metal foam deformation and the catalyst performance depending on the support porosity (75–95%) was studied.

Smorygo O. , Mikutski V. , Marukovich A. , Vialiuha Y. , Ilyushchanka A. , Mezentseva N. , Alikina G. , Vostrikov Z. , Fedorova Y. , Pelipenko V. , Bunina R. , Sadykov V.
Structured Catalyst Supports and Catalysts for the Methane Indirect Internal Steam Reforming in the Intermediate Temperature SOFC
International Journal of Heat and Mass Transfer. 2009. V.34. N23. P.9505-9514. DOI: 10.1016/j.ijhydene.2009.09.079 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	6 авг. 2009 г.
Принята к публикации:	23 сент. 2009 г.
Опубликована online:	23 окт. 2009 г.
Опубликована в печати:	1 дек. 2009 г.

Web of science:	WOS:000272722500026
Scopus:	2-s2.0-71849093416
РИНЦ:	15304885
Chemical Abstracts:	2009:1382665
Chemical Abstracts (print):	153:237281
OpenAlex:	W2024144367

БД	Цитирований
Web of science	29
Scopus	31
РИНЦ	35
OpenAlex	31