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Partial Regeneration of Model TWC After High-Temperature Aging on Engine Bench Full article

Conference Eleventh International Congress on Catalysis and Automotive Pollution Control
29-31 Oct 2018 , Brussels
Journal Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028
Output data Year: 2019, Volume: 62, Number: 1-4 SI, Pages: 324–330 Pages count : 7 DOI: 10.1007/s11244-018-1114-z
Tags Catalyst activity Cerium compounds Engines Lanthanum compounds Zirconium compounds
Authors Alikin Evgeny A. 1 , Denisov Sergey P. 1 , Vedyagin Aleksey A. 2
Affiliations
1 Ecoalliance Ltd, Novouralsk, Russia 624131
2 Boreskov Institute of Catalysis SB RAS

Funding (1)

1 The Ministry of Education and Science of the Russian Federation 14.581.21.0028 (RFMEFI58117X0028)

Abstract: Monometallic rhodium three-way catalyst supported on the ZrCeYLaO2 oxide system was prepared via impregnation method and subjected to high-temperature aging in an engine bench. The aged sample was additionally treated under model fuel-cut conditions, when the temperature was sharply reduced from 1000 °C to a room temperature. This kind of treatment was found to improve the overall catalytic activity and widen the operation window. The activated state of the catalyst was found to be stable and reproducible at repeated aging under hydrothermal conditions. Characterization of the initial and aged samples has shown that the effect of self-reactivation is connected with redistribution of agglomerated rhodium particles non-uniformly distributed on the particles of the ZrCeYLaO2 solid solution. In this case, the disadvantage of the preparation technique is appeared to have positive effect on the catalyst performance.
Cite: Alikin E.A. , Denisov S.P. , Vedyagin A.A.
Partial Regeneration of Model TWC After High-Temperature Aging on Engine Bench
Topics in Catalysis. 2019. V.62. N1-4 SI. P.324–330. DOI: 10.1007/s11244-018-1114-z WOS Scopus РИНЦ AN OpenAlex
Dates:
Published online: Dec 7, 2018
Published print: Feb 1, 2019
Identifiers:
Web of science: WOS:000461821000041
Scopus: 2-s2.0-85058102215
Elibrary: 38655701
Chemical Abstracts: 2018:2511127
OpenAlex: W2904143846
Citing:
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Scopus 10
Web of science 10
Elibrary 10
OpenAlex 10
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