One-Stage Synthesis of Propylene from Ethylene Using PdRe2O7/B2O3Al2O3 Catalyst Научная публикация
| Журнал |
Chemistry for Sustainable Development
ISSN: 1817-1818 |
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| Вых. Данные | Год: 2013, Том: 21, Номер: 1, Страницы: 47-51 Страниц : 5 | ||
| Ключевые слова | palladium sorption, ethylene, propylene, oligomerization, metathesis | ||
| Авторы |
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| Организации |
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Реферат:
Equilibrium was investigated concerning the sorption of palladium from the H2PdCl4 and Pd(NH3)4Cl2
solutions onto B2O3Al2O3 carrier. It is demonstrated that the sorption equilibrium is described by Langmuir
equation. According the results of testing the Pd/B2O3Al2O3 samples in the course of oligomerization it
has been found that the optimum content of palladium in the catalyst should be equal to 0.5 mass %,
whereas the optimum precursor of palladium should be presented by palladium chloride complex. The
catalytic properties of PdRe2O7/B2O3Al2O3 system in the one-stage propylene synthesis from ethylene
were studied. It has been demonstrated that it is possible to obtain propylene with the yield equal to 77
83 % with respect to the theoretically determined one
Библиографическая ссылка:
Buluchevskii E.A.
, Mikhailova M.S.
, Lavrenov A.V.
One-Stage Synthesis of Propylene from Ethylene Using PdRe2O7/B2O3Al2O3 Catalyst
Chemistry for Sustainable Development. 2013. V.21. N1. P.47-51. РИНЦ
One-Stage Synthesis of Propylene from Ethylene Using PdRe2O7/B2O3Al2O3 Catalyst
Chemistry for Sustainable Development. 2013. V.21. N1. P.47-51. РИНЦ
Оригинальная:
Булучевский Е.А.
, Михайлова М.С.
, Лавренов А.В.
Одностадийный синтез пропилена из этилена на катализаторе Pd-Re2O7/B2O3-Al2O3
Химия в интересах устойчивого развития. 2013. Т.21. №1. С.55-59. РИНЦ
Одностадийный синтез пропилена из этилена на катализаторе Pd-Re2O7/B2O3-Al2O3
Химия в интересах устойчивого развития. 2013. Т.21. №1. С.55-59. РИНЦ
Идентификаторы БД:
| РИНЦ: | 46564029 |
Цитирование в БД:
| БД | Цитирований |
|---|---|
| РИНЦ | 6 |