Selective Aqueous-Phase Hydrogenation of Furfural to Cyclopentanol over PdRu/C Catalyst | Sciact - CRIS-system of Boreskov Institute of Catalysis

Selective Aqueous-Phase Hydrogenation of Furfural to Cyclopentanol over PdRu/C Catalyst Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 2017, Volume: 66, Number: 4, Pages: 673-676 Pages count : 4

Tags

furfural, catalytic hydrogenation, bimetallic catalyst, cyclopentanol

Authors

Mironenko R.M. ^1,2 , Belskaya O.B. ^1,3 , Lavrenov A.V. ¹ , Likholobov V.A. ^1,3,4

Affiliations

1	Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences
2	Dostoevsky Omsk State University
3	Omsk State Technical University
4	Omsk Scientific Center, Siberian Branch of the Russian Academy of Sciences

The bimetallic PdRu catalyst supported on carbon nanotubes were found ot provide an efficient synthesis of cyclopentanol in aqueousphase hydrogenation of furfural. Under the chosen reaction conditions (temperature of 473 K, total pressure of 8 MPa), the selectivity towards cyclopentanol reaches 77% at a complete conversion of furfural. A high activity of this catalyst can be associated with changes in the electronic state and dispersion of the supported metals caused by their mutual interaction and formation of PdRu alloy.

Mironenko R.M. , Belskaya O.B. , Lavrenov A.V. , Likholobov V.A.
Selective Aqueous-Phase Hydrogenation of Furfural to Cyclopentanol over PdRu/C Catalyst
Russian Chemical Bulletin. 2017. V.66. N4. P.673-676. РИНЦ ANCAN

Мироненко Р.М. , Бельская О.Б. , Лавренов А.В. , Лихолобов В.А.
Селективное образование циклопентанола при аквафазном гидрировании фурфурола в присутствии катализатора PdRu/C
Известия Академии наук. Серия химическая. 2017. №4. С.673-676. РИНЦ

Submitted:	Jul 15, 2016
Accepted:	Nov 1, 2016
Published print:	Apr 1, 2017
Published online:	Sep 2, 2017

Elibrary:	31064511
Chemical Abstracts:	2017:1448435
Chemical Abstracts (print):	167:381543

DB	Citing
Elibrary	12