Catalytic Oxidation of CO to CO2 by Dioxygen in the Presence of Palladium and Heteropolycomplexes HxPM12-nVnO4-0(3+n-x) | Sciact - CRIS-system of Boreskov Institute of Catalysis

Catalytic Oxidation of CO to CO2 by Dioxygen in the Presence of Palladium and Heteropolycomplexes HxPM12-nVnO4-0(3+n-x) Full article

Conference

5th International Symposium on Relations Between Homogeneous and Heterogeneous Catalysis
15-19 Jul 1986 , Новосибирск

Source

Homogeneous and Heterogeneous Catalysis: Proceedings of the Fifth International Symposium on Relations Between Homogeneous and Heterogeneous Catalysis, USSR
Compilation, CRC Press. 1986. 1170 c. ISBN 9789067640732.

Output data

Year: 1986, Pages: 259-272 Pages count : 11

Tags

carbon monoxide oxidation catalyst heteropoly palladium

Authors

Kuznetsova L.I. ¹ , Pavlova S.N. ¹ , Zhizhina E.G. ¹ , Matveev K.I. ¹ , Popovskii V.V. ¹ , Sazonov V.A. ¹ , Pashis A.V. ¹ , Fenelonov V.B. ¹

Affiliations

1	Institute of Catalysis, Novosibirsk 630090, USSR

The catalytic of CO to CO2 in aqueous solutions of PdSO4 and NaxH3+n-xM12-nVnO40 heteropoly-complexes was studied. By supporting the complexes and Pd(II) on SiO2, it is possible to obtain catalysts for CO oxidation by mol. O, which are active at 15-40° in the presence of H2O vapor. Reaction mechanisms of CO oxidation on supported and homogeneous catalysts are similar. The support pore structure has a pronounced effect on the catalytic activity. Intermediate active complexes of Pd(I) are formed on the surface both from Pd(II) and metallic Pd.

Kuznetsova L.I. , Pavlova S.N. , Zhizhina E.G. , Matveev K.I. , Popovskii V.V. , Sazonov V.A. , Pashis A.V. , Fenelonov V.B.
Catalytic Oxidation of CO to CO2 by Dioxygen in the Presence of Palladium and Heteropolycomplexes HxPM12-nVnO4-0(3+n-x)
In compilation Homogeneous and Heterogeneous Catalysis: Proceedings of the Fifth International Symposium on Relations Between Homogeneous and Heterogeneous Catalysis, USSR. – CRC Press., 1986. – C.259-272. – ISBN 9789067640732. ANCAN

Chemical Abstracts:	1987:584438
Chemical Abstracts (print):	107:184438

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