Catalytic Condensation of Glycolaldehyde and Glyceraldehyde with Formaldehyde in Neutral and Weakly Alkaline Aqueous Media: Kinetics and Mechanism Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
||||
|---|---|---|---|---|---|
| Output data | Year: 2009, Volume: 50, Number: 2, Pages: 297-303 Pages count : 7 DOI: 10.1134/S0023158409020219 | ||||
| Tags | Monosaccharide; Apparent Activation Energy; Glyceraldehyde; Apparent Rate Constant; Aldol Condensation | ||||
| Authors |
|
||||
| Affiliations |
|
Funding (3)
| 1 | The Ministry of Education and Science of the Russian Federation | 2.1.1.1969 |
| 2 | Президиум РАН | |
| 3 | Council for Grants of the President of the Russian Federation | НШ-6526.2006.3 |
Abstract:
The kinetics of glycolaldehyde and glyceraldehyde condensation with formaldehyde in a neutral aqueous medium in the presence of homogeneous phosphates and in a weakly alkaline medium in the presence of MgO was studied. The temperature dependences of the observed kinetic constants and the apparent activation energies of the reactions were determined. A reaction scheme for the interaction of lower monosaccharides with formaldehyde was derived from analyses of the reaction products.
Cite:
Delidovich I.V.
, Simonov A.N.
, Pestunova O.P.
, Parmon V.N.
Catalytic Condensation of Glycolaldehyde and Glyceraldehyde with Formaldehyde in Neutral and Weakly Alkaline Aqueous Media: Kinetics and Mechanism
Kinetics and Catalysis. 2009. V.50. N2. P.297-303. DOI: 10.1134/S0023158409020219 WOS Scopus РИНЦ ANCAN OpenAlex
Catalytic Condensation of Glycolaldehyde and Glyceraldehyde with Formaldehyde in Neutral and Weakly Alkaline Aqueous Media: Kinetics and Mechanism
Kinetics and Catalysis. 2009. V.50. N2. P.297-303. DOI: 10.1134/S0023158409020219 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Делидович И.В.
, Симонов А.Н.
, Пестунова О.П.
, Пармон В.Н.
Кинетика и механизм каталитической конденсации гликолевого и глицеринового альдегидов с формальдегидом в нейтральной и слабощелочной водных средах
Кинетика и катализ. 2009. Т.50. №2. С.314-321. РИНЦ
Кинетика и механизм каталитической конденсации гликолевого и глицеринового альдегидов с формальдегидом в нейтральной и слабощелочной водных средах
Кинетика и катализ. 2009. Т.50. №2. С.314-321. РИНЦ
Dates:
| Submitted: | Mar 28, 2008 |
| Published print: | Mar 1, 2009 |
| Published online: | Apr 24, 2009 |
Identifiers:
| Web of science: | WOS:000265499100021 |
| Scopus: | 2-s2.0-65349151867 |
| Elibrary: | 14718803 |
| Chemical Abstracts: | 2009:496080 |
| Chemical Abstracts (print): | 151:100701 |
| OpenAlex: | W2090329842 |