Sciact
  • EN
  • RU

Using Low-Temperature Molten Dialkylimidazole Salts in the Catalytic Reactions of Alkylation and Hydrodechlorination Full article

Journal Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555
Output data Year: 2018, Volume: 10, Number: 4, Pages: 313-320 Pages count : 8 DOI: 10.1134/S2070050418040086
Tags ionic liquids, polychlorinated aromatic compounds, persistent organic pollutants, condensation, hydrodechlorination, alkylation
Authors Klimenko A.S. 1,2 , Prikhod'ko S.A. 1 , Beskopyl’nyi A.M. 1,2 , Tertishnikov I.V. 2 , Adonin N.Yu 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2 Volgograd Branch, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Volgograd, 400097 Russia

Funding (1)

1 Federal Agency for Scientific Organizations 0303-2016-0007

Abstract: The possibility of preparing a mixture of 1,3-dialkylimidazole salts from commercially available reagents via multicomponent condensation is considered. The main factors affecting the yield of the target product, and the experimental data needed for scaling up the process, are discussed. It is shown that the prepared mixtures are close in some key properties (e.g., viscosity at different temperatures, heat capacity) to the pure salts. The possibility of using the prepared salts as solvents for catalytic hydrodechlorination and catalyst components for the alkylation of aromatic compounds is demonstrated.
Cite: Klimenko A.S. , Prikhod'ko S.A. , Beskopyl’nyi A.M. , Tertishnikov I.V. , Adonin N.Y.
Using Low-Temperature Molten Dialkylimidazole Salts in the Catalytic Reactions of Alkylation and Hydrodechlorination
Catalysis in Industry. 2018. V.10. N4. P.313-320. DOI: 10.1134/S2070050418040086 WOS Scopus РИНЦ OpenAlex
Original: Клименко А.С. , Приходько С.А. , Бескопыльный А.М. , Тертишников И.В. , Адонин Н.Ю.
Применение низкотемпературных расплавов смесей солей диалкилимидазолия в каталитических реакциях алкилирования и гидродехлорирования
Катализ в промышленности. 2018. Т.18. №4. С.48-56. DOI: 10.18412/1816-0387-2018-4-48-56 РИНЦ AN OpenAlex
Dates:
Submitted: Feb 26, 2018
Accepted: Feb 26, 2018
Published print: Oct 1, 2018
Published online: Jan 14, 2019
Identifiers:
Web of science: WOS:000455594600007
Scopus: 2-s2.0-85060138239
Elibrary: 38659350
OpenAlex: W2909414865
Citing:
DB Citing
Elibrary 1
Altmetrics: