Effect of Silicon Dioxide on the Formation of the Phase Composition and Pore Structure of Titanium Dioxide with the Anatase Structure Full article
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Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2009, Volume: 50, Number: 5, Pages: 760-767 Pages count : 8 DOI: 10.1134/S002315840905019X | ||
| Tags | Rutile; Anatase Phase; Tetraethyl Orthosilicate; Nanocrystalline Structure; Anatase Structure | ||
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Abstract:
The formation of the structure of titanium dioxide modified with silicon dioxide, which was introduced as tetraethyl orthosilicate, was studied. It was found that the formation of the nanocrystalline structure of TiO2 occurred upon the modification of titanium dioxide with silicon dioxide. This nanocrystalline structure of TiO2 was formed by highly dispersed anatase particles of size 6–10 nm stabilized by silicon oxide layers, which were formed upon the decomposition of tetraethyl orthosilicate. An increase in the modifier concentration resulted in a deceleration of the growth of anatase particles and an increase in the temperature of the phase transition of anatase to rutile. It was found that the anatase phase in the samples containing 5–15 wt % SiO2 was stable up to 1000°C. The stabilization of highly dispersed anatase particles facilitated the retention of the developed fine-pore structure of xerogels with a pore diameter of 4 nm up to 900°C.
Cite:
Zenkovets G.A.
, Gavrilov V.Y.
, Shutilov A.A.
, Tsybulya S.V.
Effect of Silicon Dioxide on the Formation of the Phase Composition and Pore Structure of Titanium Dioxide with the Anatase Structure
Kinetics and Catalysis. 2009. V.50. N5. P.760-767. DOI: 10.1134/S002315840905019X WOS Scopus РИНЦ OpenAlex ANCAN
Effect of Silicon Dioxide on the Formation of the Phase Composition and Pore Structure of Titanium Dioxide with the Anatase Structure
Kinetics and Catalysis. 2009. V.50. N5. P.760-767. DOI: 10.1134/S002315840905019X WOS Scopus РИНЦ OpenAlex ANCAN
Original:
Зенковец Г.А.
, Гаврилов В.Ю.
, Шутилов А.А.
, Цыбуля С.В.
Влияние добавок диоксида кремния на формирование фазового состава и пористой структуры диоксида титана со структурой анатаза
Кинетика и катализ. 2009. Т.50. №5. С.790-797. РИНЦ
Влияние добавок диоксида кремния на формирование фазового состава и пористой структуры диоксида титана со структурой анатаза
Кинетика и катализ. 2009. Т.50. №5. С.790-797. РИНЦ
Dates:
| Submitted: | May 8, 2008 |
| Published print: | Sep 1, 2009 |
| Published online: | Oct 11, 2009 |
Identifiers:
| ≡ Web of science: | WOS:000270681900019 |
| ≡ Scopus: | 2-s2.0-70350037726 |
| ≡ Elibrary: | 15307817 |
| ≡ OpenAlex: | W1975424398 |
| ≡ Chemical Abstracts: | 2009:1249169 |
| ≡ Chemical Abstracts (print): | 153:18808 |