CuFeAl-Composite Catalysts of Oxidation of Gasification Products of Solid Fuels: In situ XAS and XRD Study Научная публикация
Конференция |
17th International Conference on X-ray Absorption Fine Structure 22-27 июл. 2018 , Kraków |
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Журнал |
Radiation Physics and Chemistry
ISSN: 0969-806X , E-ISSN: 1879-0895 |
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Вых. Данные | Год: 2020, Том: 175, Номер: SI, Номер статьи : 108071, Страниц : 4 DOI: 10.1016/j.radphyschem.2018.11.025 | ||||||
Ключевые слова | In situ XASIn situ XRDCuFeAl-composite catalystsCO oxidationCatalytic combustion | ||||||
Авторы |
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Организации |
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Информация о финансировании (1)
1 | Российский научный фонд | 17-73-20157 |
Реферат:
The reduction of high-active FeAl and CuFeAl composite catalysts was investigated in situ by XRD and XAS in the temperature range between 100 and 600 °C. It was found that the fresh catalysts consist of Fe2O3 and Al2O3 phases only. The Al3+ cations partially dissolute in the Fe2O3 lattice. The addition of copper to the Fe-Al catalyst leads to formation of highly dispersed CuO nanoparticles and mixed oxide with a spinel-type crystalline structure similar to that of CuFe2O4. The low-temperature reduction of Cu2+ to Cu0 accelerates the Fe2O3 → Fe3O4 and FeO → Fe0 transformations. In the presence of oxygen we did not observe the reduction of Cu and Fe to the metallic state. This means that the oxidation of CO over FeAl and CuFeAl composite catalysts proceeds via a redox mechanism.
Библиографическая ссылка:
Saraev A.A.
, Tsapina A.M.
, Fedorov A.V.
, Trigub A.L.
, Bulavchenko O.A.
, Vinokurov Z.S.
, Zubavichus Y.V.
, Kaichev V.V.
CuFeAl-Composite Catalysts of Oxidation of Gasification Products of Solid Fuels: In situ XAS and XRD Study
Radiation Physics and Chemistry. 2020. V.175. NSI. 108071 :1-4. DOI: 10.1016/j.radphyschem.2018.11.025 WOS Scopus РИНЦ CAPlus OpenAlex
CuFeAl-Composite Catalysts of Oxidation of Gasification Products of Solid Fuels: In situ XAS and XRD Study
Radiation Physics and Chemistry. 2020. V.175. NSI. 108071 :1-4. DOI: 10.1016/j.radphyschem.2018.11.025 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
Поступила в редакцию: | 30 сент. 2018 г. |
Принята к публикации: | 25 нояб. 2018 г. |
Опубликована online: | 26 нояб. 2018 г. |
Опубликована в печати: | 1 окт. 2020 г. |
Идентификаторы БД:
Web of science: | WOS:000543372500036 |
Scopus: | 2-s2.0-85058150349 |
РИНЦ: | 45548339 |
Chemical Abstracts: | 2018:2537486 |
OpenAlex: | W2903540679 |