Effective Pd/C Catalyst for Chlorobenzene and Hexachlorobenzene Hydrodechlorination by Direct Pyrolysis of Sawdust Impregnated with Palladium Nitrate | Sciact - CRIS-система Института катализа

Effective Pd/C Catalyst for Chlorobenzene and Hexachlorobenzene Hydrodechlorination by Direct Pyrolysis of Sawdust Impregnated with Palladium Nitrate Научная публикация

Журнал

Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905

Вых. Данные

Год: 2016, Том: 77, Страницы: 37-41 Страниц : 5 DOI: 10.1016/j.catcom.2016.01.013

Ключевые слова

Pd catalyst Sawdust Hydrodechlorination Hexachlorobenzene Chlorobenzene Pyrolysis

Авторы

Klokov S.V. ^1,2 , Lokteva E.S. ^1,2 , Golubina E.V. ^1,2 , Maslakov K.I. ^1,2 , Levanov A.V. ¹ , Chernyak S.A. ¹ , Likholobov V.A. ²

Организации

1	Lomonosov Moscow State University, Chemistry Department, 1–3, Leninskie Gory, Moscow 119991, Russia
2	Institute of Hydrocarbons Processing of the Siberian Branch of the RAS, 54, Neftezavodskaya str., Omsk 644040, Russia

Информация о финансировании (1)

Российский научный фонд

14-33-00018 (114123040010)

Two Pd/C catalysts were prepared by pyrolysis of Pd(NO3)2 impregnated sawdust. At equal pyrolysis time slow ramping with shorter isothermal heating resulted in 0.9 wt.% Pd/C-S1 sample comprising carbon support with some oxygen-containing moieties and Pd0 with 2.6 nm average particle size (APS) partially decorated with carbon shell, whereas fast temperature ramping and long isothermal heating provided 0.6 wt.% Pd/C-S2 containing Pd0 with 3.7 nm APS, with larger fraction of carbon decorated particles. Pd/C-S1 is slightly more efficient than Pd/C-S2 in gas phase chlorobenzene hydrodechlorination to benzene at 100–250 °C. Only Pd/C-S1 provides hexachlorobenzene hydrodechlorination in liquid phase due to lower APS and probably smaller PdCx content.

Klokov S.V. , Lokteva E.S. , Golubina E.V. , Maslakov K.I. , Levanov A.V. , Chernyak S.A. , Likholobov V.A.
Effective Pd/C Catalyst for Chlorobenzene and Hexachlorobenzene Hydrodechlorination by Direct Pyrolysis of Sawdust Impregnated with Palladium Nitrate
Catalysis Communications. 2016. V.77. P.37-41. DOI: 10.1016/j.catcom.2016.01.013 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	8 окт. 2015 г.
Принята к публикации:	15 янв. 2016 г.
Опубликована online:	16 янв. 2016 г.
Опубликована в печати:	5 мар. 2016 г.

Web of science:	WOS:000371186900009
Scopus:	2-s2.0-84955244485
РИНЦ:	26824522
Chemical Abstracts:	2016:139613
Chemical Abstracts (print):	164:225550
OpenAlex:	W2286563652

БД	Цитирований
Web of science	14
Scopus	15
OpenAlex	16