The Effect of Preparation Conditions of Pd/C Catalyst on Its Activity and Selectivity in the Aqueous-Phase Hydrogenation of 2,4,6-Trinitrobenzoic Acid Научная публикация
| Конференция |
7th International Symposium on Carbon for Catalysis 12-16 июн. 2016 , Strasbourg |
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| Журнал |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
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| Вых. Данные | Год: 2018, Том: 301, Страницы: 258-265 Страниц : 8 DOI: 10.1016/j.cattod.2017.02.037 | ||||||||||
| Ключевые слова | Trinitrobenzoic acid Aqueous-phase hydrogenation Palladium catalyst Particle size Specific catalytic activity Selectivity | ||||||||||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Российский фонд фундаментальных исследований | 16-03-00601 (АААА-А16-116021950037-7) |
Реферат:
The effect of the nature of alkaline agent and pH value of hydrolysis of Pd(II) chloride complex into palladium polynuclear hydroxo complexes, as precursor of active component in Pd/C catalyst, on the dispersion of palladium particles supported on carbon material Sibunit was revealed. It was shown that an increase in the particle size of supported palladium enhances the specific catalytic activity in hydrogenation of 2,4,6-trinitrobenzoic acid and changes the direction of the transformation (increases the fraction of non-aromatic intermediate, cyclohexane-1,3,5-trione trioxime, in the products). The results obtained are essential for optimizing the particle size of supported palladium in selective hydrogenation of polyfunctional organic compounds.
Библиографическая ссылка:
Belskaya O.B.
, Mironenko R.M.
, Talsi V.P.
, Rodionov V.A.
, Gulyaeva T.I.
, Sysolyatin S.V.
, Likholobov V.A.
The Effect of Preparation Conditions of Pd/C Catalyst on Its Activity and Selectivity in the Aqueous-Phase Hydrogenation of 2,4,6-Trinitrobenzoic Acid
Catalysis Today. 2018. V.301. P.258-265. DOI: 10.1016/j.cattod.2017.02.037 WOS Scopus РИНЦ OpenAlex CAPlusCA
The Effect of Preparation Conditions of Pd/C Catalyst on Its Activity and Selectivity in the Aqueous-Phase Hydrogenation of 2,4,6-Trinitrobenzoic Acid
Catalysis Today. 2018. V.301. P.258-265. DOI: 10.1016/j.cattod.2017.02.037 WOS Scopus РИНЦ OpenAlex CAPlusCA
Даты:
| Поступила в редакцию: | 29 нояб. 2016 г. |
| Принята к публикации: | 27 февр. 2017 г. |
| Опубликована online: | 9 мар. 2017 г. |
| Опубликована в печати: | 1 мар. 2018 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:000417054300033 |
| ≡ Scopus: | 2-s2.0-85014709950 |
| ≡ РИНЦ: | 31038069 |
| ≡ OpenAlex: | W2594348905 |
| ≡ Chemical Abstracts: | 2017:404732 |
| ≡ Chemical Abstracts (print): | 167:571507 |