Influence of Polymeric Template Impurities on Photocatalytic Properties of Bulk Macroporous TiO2 under Visible Light Irradiation in the Gas Phase Oxidation of Acetone Full article
| Journal |
Reaction Kinetics, Mechanisms and Catalysis
ISSN: 1878-5190 , E-ISSN: 1878-5204 |
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| Output data | Year: 2019, Volume: 127, Number: 1, Pages: 53–67 Pages count : 15 DOI: 10.1007/s11144-019-01539-3 | ||||
| Tags | Gas-phase oxidation, Macroporous TiO2, Photocatalysis, Template-assisted method, Visible light | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0010 |
Abstract:
Macroporous oxides are often prepared by template method with polymeric spheres, however, these polymeric spheres synthesized by emulsion polymerization using different initiators, most commonly contain S or/and N chemical residues. We have found that these template-originated impurities are not completely removed after thermal treatment of composites at ~ 500 °C, thus, influencing surface acidic properties and photocatalytic performance of the catalysts. The research is focused on the influence of different types of chemical residues left after incomplete polymer elimination on photocatalytic activity.
Cite:
Sankova N.
, Semeykina V.
, Selishchev D.
, Glazneva T.
, Parkhomchuk E.
, Kolinko P.
Influence of Polymeric Template Impurities on Photocatalytic Properties of Bulk Macroporous TiO2 under Visible Light Irradiation in the Gas Phase Oxidation of Acetone
Reaction Kinetics, Mechanisms and Catalysis. 2019. V.127. N1. P.53–67. DOI: 10.1007/s11144-019-01539-3 WOS Scopus РИНЦ РИНЦ AN OpenAlex
Influence of Polymeric Template Impurities on Photocatalytic Properties of Bulk Macroporous TiO2 under Visible Light Irradiation in the Gas Phase Oxidation of Acetone
Reaction Kinetics, Mechanisms and Catalysis. 2019. V.127. N1. P.53–67. DOI: 10.1007/s11144-019-01539-3 WOS Scopus РИНЦ РИНЦ AN OpenAlex
Dates:
| Submitted: | Nov 29, 2018 |
| Accepted: | Jan 13, 2019 |
| Published online: | Jan 28, 2019 |
| Published print: | Jun 15, 2019 |
Identifiers:
| Web of science: | WOS:000468213500006 |
| Scopus: | 2-s2.0-85060814569 |
| Elibrary: | 38654283 | 41788882 |
| Chemical Abstracts: | 2019:628203 |
| OpenAlex: | W2912384569 |
Citing:
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