Clays Pillared by Zirconia Nanoparticles: Structure, Adsorption and Catalytic Properties Научная публикация
| Конференция |
2005 MRS Spring Meeting. Symposium R - Nanoporous and Nanostructured Materials for Catalysis, Sensor and Gas Separation Applications 28 мар. - 1 апр. 2005 , San Francisco, California |
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| Сборник | Nanoporous and Nanostructured Materials for Catalysis, Sensor and Gas Separation Applications : Proceedings of a meeting held 28 March - 1 April 2005, San Francisco, California, USA. Symposium A at the 2005 MRS Spring Meeting Сборник, Cambridge University Press ( CUP ) / Materials Research Society ( MRS ). 2006. 303 c. ISBN 9781558998308. |
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| Журнал |
MRS Online Proceedings Library
ISSN: 1946-4274 |
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| Вых. Данные | Год: 2005, Том: 876, Номер статьи : 821, Страниц : 6 DOI: 10.1557/proc-876-r8.21 | ||||||
| Ключевые слова | Adsorption; Catalysis; Clay; Condensation; Density functional theory; Monte Carlo methods; Porosity; Propylene; Zirconia | ||||||
| Авторы |
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| Организации |
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Реферат:
Modeling of high resolution nitrogen adsorption isotherms by the Grand Canonical Monte Carlo (GCMC) method for zirconia-pillared clays containing 20 wt.% of ZrO2 revealed that the pillars are comprised of separate Zr4(μ-OH)8(OH)m (H2O)n units (Zr4 tetramers) and their dimers (Zr8 complexes) as sheets or loose 3D structures. This agrees with the results of modeling of the condensation process in solution using the Density Functional Theory approach (DFT) and the semiempirical PM3 method. Bridging and terminal hydroxyls strongly bound with Zr cations are involved in anchoring supported Cu cations and Pt. This nanostructure of the active component as well as the developed micro- and mesoporosity appear to be responsible for the high performance of Pt+Cu/ZrPILC catalysts in the NOx selective reduction by propylene and decane in realistic feeds.
Библиографическая ссылка:
Sadykov V.A.
, Kuznetsova T.G.
, Bunina R.V.
, Mezentseva N.V.
, Efremov D.K.
, Avdeev V.I.
, Doronin V.P.
, Kuznetsov V.L.
, Volodin A.M.
, Paukshtis E.A.
, Alikina G.M.
, Matyshak V.A.
, Lunin V.V.
Clays Pillared by Zirconia Nanoparticles: Structure, Adsorption and Catalytic Properties
В сборнике Nanoporous and Nanostructured Materials for Catalysis, Sensor and Gas Separation Applications : Proceedings of a meeting held 28 March - 1 April 2005, San Francisco, California, USA. Symposium A at the 2005 MRS Spring Meeting. – Cambridge University Press ( CUP ) / Materials Research Society ( MRS )., 2005. – Т.1. – ISBN 9781558998308. DOI: 10.1557/proc-876-r8.21 Scopus РИНЦ CAPlusCA OpenAlex
Clays Pillared by Zirconia Nanoparticles: Structure, Adsorption and Catalytic Properties
В сборнике Nanoporous and Nanostructured Materials for Catalysis, Sensor and Gas Separation Applications : Proceedings of a meeting held 28 March - 1 April 2005, San Francisco, California, USA. Symposium A at the 2005 MRS Spring Meeting. – Cambridge University Press ( CUP ) / Materials Research Society ( MRS )., 2005. – Т.1. – ISBN 9781558998308. DOI: 10.1557/proc-876-r8.21 Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Опубликована online: | 15 февр. 2011 г. |
Идентификаторы БД:
| Scopus: | 2-s2.0-34250025636 |
| РИНЦ: | 15042081 |
| Chemical Abstracts: | 2008:741241 |
| Chemical Abstracts (print): | 149:206723 |
| OpenAlex: | W2269302501 |