Combustion Characteristics and Structure of Carbon Nanotube/Titanium Composites | Sciact - CRIS-system of Boreskov Institute of Catalysis

Combustion Characteristics and Structure of Carbon Nanotube/Titanium Composites Full article

Journal

Journal of Thermal Analysis and Calorimetry
ISSN: 1388-6150 , E-ISSN: 1572-8943

Output data

Year: 2019, Volume: 137, Number: 6, Pages: 1903-1910 Pages count : 8 DOI: 10.1007/s10973-019-08109-8

Tags

Ball milling, Multi-walled carbon nanotubes, Thermal explosion, Titanium, Titanium carbide

Authors

Korchagin Michail A. ^1,2,3 , Gabdrashova Sholpan E. ⁴ , Dudina Dina V. ^1,2,5 , Bokhonov Boris B. ^1,6 , Bulina Natalia V. ¹ , Kuznetsov Vladimir L. ⁷ , Ishchenko Arcady V. ⁷

Affiliations

1	Institute of Solid State Chemistry and Mechanochemistry, SB RAS, Kutateladze str. 18, Novosibirsk, Russia 630128
2	Novosibirsk State Technical University, K. Marx Ave. 20, Novosibirsk, Russia 630073
3	National Research Tomsk State University, Lenin Ave. 36, Tomsk, Russia 634050
4	Al-Farabi Kazakh National University, Al-Farabi Ave. 71, Almaty, Kazakhstan 050040
5	Lavrentyev Institute of Hydrodynamics, SB RAS, Lavrentyev Ave. 15, Novosibirsk, Russia 630090
6	Novosibirsk State University, Pirogova str. 2, Novosibirsk, Russia 630090
7	Boreskov Institute of Catalysis, SB RAS, Lavrentyev Ave. 5, Novosibirsk, Russia 630090

Funding (1)

Federal Agency for Scientific Organizations

0301-2016-0021 (АААА-А17-117030310277-6)

Reactivity of nanosized objects is a hot topic in modern solid-state chemistry and materials science. The present work is focused on the interaction between multi-walled carbon nanotubes (MWCNTs) and metallic titanium during high-energy ball milling and thermal explosion, a rapid temperature rise in a mixture caused by an exothermic reaction ignited by external heating and occurring throughout the sample volume. A fundamental property of the nanocomposite mixture—the ability of its components to react in the combustion mode—is explained; an analysis of the dependence of the combustion characteristics of the nanocomposites on the milling duration of powder mixtures is provided. The phase and structural transformations of the Ti-MWCNT mixtures have been analyzed using X-ray diffraction and transmission electron microscopy. It was found that the ball-milled powders contain nanostructured titanium, nanotube fragments, amorphous carbon and nanosized carbon-deficient titanium carbide TiCx. Within the nanocomposite powder particles, TiCx nanoparticles are covered with layers of amorphous carbon. Thermal explosion was observed in Ti-4mass%MWCNT mixtures milled for 1.5–7 min. Shorter milling times were apparently not sufficient for establishing a proper interfacial contact, while longer milling times led to the extensive formation of titanium carbide TiCx, which acted as a barrier lowering the heat release by the mixture upon ignition. Both the ignition temperature of Ti-4mass%MWCNT and the maximum temperature developed during thermal explosion decrease with the milling time. A comparison of the behavior of MWCNT with that of carbon black under conditions of thermal explosion in the mixtures with titanium is also presented.

Korchagin M.A. , Gabdrashova S.E. , Dudina D.V. , Bokhonov B.B. , Bulina N.V. , Kuznetsov V.L. , Ishchenko A.V.
Combustion Characteristics and Structure of Carbon Nanotube/Titanium Composites
Journal of Thermal Analysis and Calorimetry. 2019. V.137. N6. P.1903-1910. DOI: 10.1007/s10973-019-08109-8 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Jul 27, 2018
Accepted:	Feb 15, 2019
Published online:	Mar 2, 2019
Published print:	Sep 1, 2019

Web of science:	WOS:000481773000007
Scopus:	2-s2.0-85062726343
Elibrary:	38689008
Chemical Abstracts:	2019:671612
OpenAlex:	W2920653024

DB	Citing
Scopus	6
Elibrary	6
Web of science	6
OpenAlex	6